Improvement of the Surface Properties of Polystyrene Sheets via UV Curable Organic-Inorganic Hybrid Coatings

• Authors: H. Demirer , İ. Kartal , M. Çakir
• Languages of publication: EN

Abstracts

EN

This study describes the synthesis of silane terminated urethane, aimed at adding into epoxy acrylate, for the coating purposes. For this aim, firstly, silane terminated urethane was synthesized by the reaction between poly(hexamethylene carbonate) diol and 3-isocyanatopropyltrimethoxysilane. Pre-hydrolyzed TEOS and MEMO mixture was added to the silane terminated urethane. This solution was then mixed with organic part (epoxy acrylate and HDDA) to obtain hybrid solutions. Different organic-inorganic hybrid formulations were applied on polystyrene sheet surfaces by using applicators. The performance of the coatings on polystyrene sheets was investigated by applying physical and chemical tests. The results have shown that physical and chemical properties of polystyrene sheet surfaces were significantly improved.

Keywords

EN

68.37.-d

Discipline

• 68.37.-d: Microscopy of surfaces, interfaces, and thin films

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2017
• Volume: 131
• Issue: 3
• Pages: 555-558

Dates

published

2017-03

Contributors

author

H. Demirer

• Marmara University, Faculty of Technology, 34720 Istanbul, Turkey

author

İ. Kartal

• Marmara University, Faculty of Technology, 34720 Istanbul, Turkey

author

M. Çakir

• Marmara University, Faculty of Technology, 34720 Istanbul, Turkey

References

• [1] J. Maul, B.G. Frushour, J.R. Kontoff, H. Eichenauer, K-H. Ott, C. Schade, Polystyrene and Styrene Copolymers in: Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, 2007, doi: 10.1002/14356007.a21_615.pub2
• [2] M. Cakir, I. Kartal, Z. Yildiz, Text. Res. J. 84, 1528 (2014), doi: 10.1177/0040517514525883
• [3] M. V. Kahraman, Z.S. Akdemir, I. Kartal, N. Kayaman-Apohan, A. Gungor, Polym. Adv. Technol. 22, 981 (2009), doi: 10.1002/pat.1604
• [4] R.D. van de Grampel, W. Ming, W.J.H. van Gennip, F. van der Velden, J. Laven, J.W. Niemantsverdriet, R. van der Linde, Polymer 46, 10531 (2005), doi: 10.1016/j.polymer.2005.08.024
• [5] Z. Zong, J. He, M.D. Soucek, Progress Organic Coat. 53, 83 (2005), doi: 10.1016/j.porgcoat.2004.08.008
• [6] V. Kumar, N. Misra, J. Paul, Y.K. Bhardwaj, N.K. Goel, S. Francis, K.S.S. Sarma, L. Varshney, Progress Organic Coat. 76, 1119 (2013), doi: 10.1016/j.porgcoat.2013.03.010
• [7] J. Gao, X. Wang, Y. Wei, W. Yang, J. Fluor. Chem. 127, 282 (2006), doi: 10.1016/j.jfluchem.2005.12.002
• [8] M. Cakir, I. Kartal, H. Demirer, R. Samur, Sci. Res. Essays 7, 805 (2012), doi: 10.5897/SRE11.1682
• [9] İ. Kartal, Asian J. Chem. 26, 6018 (2014), doi: 10.14233/ajchem.2014.16485
• [10] H. Beytut M. Çakır, İ. Kartal, M. Sengül, D. Tutak, Asian J. Chem. 27, 3854 (2015), doi: 10.14233/ajchem.2015.19033

Identifiers

DOI

10.12693/APhysPolA.131.555