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2017 | 131 | 2 | 311-317
Article title

Identification of Trace 2-Chloropropene with a New Chirped Pulse Microwave Spectrometer

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EN
Abstracts
EN
The design of a new chirped pulse, Fourier-transform microwave spectrometer for recording broadband rotational spectra of supersonic expansion samples is described. The spectrometer can record spectral windows of width of up to 2.2 GHz over the 2-18 GHz frequency region. It is complemented by a new FFT program with several novel features. Tests of the spectrometer revealed the presence of an initially unknown volatile trace molecule in a sample of 2,2-dichloropropane (DCP). The broadband nature of the new spectrometer allowed rapid assignment of the new species as 2-chloropropene, CH₃CCl=CH₂ (2CP). Additional mm wave measurements combined with analysis of previous DCP spectra up to 311 GHz allow us to report the hitherto most precise spectroscopic constants for 2CP.
Publisher

Year
Volume
131
Issue
2
Pages
311-317
Physical description
Dates
published
2017-02
received
2017-02-13
Contributors
author
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv131n219kz
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