Preferences help
enabled [disable] Abstract
Number of results
2017 | 131 | 2 | 311-317
Article title

Identification of Trace 2-Chloropropene with a New Chirped Pulse Microwave Spectrometer

Title variants
Languages of publication
The design of a new chirped pulse, Fourier-transform microwave spectrometer for recording broadband rotational spectra of supersonic expansion samples is described. The spectrometer can record spectral windows of width of up to 2.2 GHz over the 2-18 GHz frequency region. It is complemented by a new FFT program with several novel features. Tests of the spectrometer revealed the presence of an initially unknown volatile trace molecule in a sample of 2,2-dichloropropane (DCP). The broadband nature of the new spectrometer allowed rapid assignment of the new species as 2-chloropropene, CH₃CCl=CH₂ (2CP). Additional mm wave measurements combined with analysis of previous DCP spectra up to 311 GHz allow us to report the hitherto most precise spectroscopic constants for 2CP.
Physical description
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
  • Institute of Physics, Polish Academy of Sciences, Aleja Lotnikow 32/46, PL-02668 Warsaw, Poland
  • [1] T.J. Balle, W.H. Flygare, Rev. Sci. Instrum. 52, 33 (1981), doi: 10.1063/1.1136443
  • [2] W. Caminati, J.-U. Grabow, in: Frontiers of Molecular Spectroscopy, Ed. J. Laane, Elsevier, 2009, p. 455, doi: 10.1016/B978-0-444-53175-9.00015-5
  • [3] Z. Kisiel, J. Kosarzewski, L. Pszczółkowski, Acta. Phys. Pol. A 92, 507 (1997), doi: 10.12693/APhysPolA.92.507
  • [4] Z. Kisiel, E. Białkowska-Jaworska, L. Pszczółkowski, A. Milet, C. Struniewicz, R. Moszynski, J. Sadlej, J. Chem. Phys. 112, 5767 (2000), doi: 10.1063/1.481152
  • [5] Z. Kisiel, B.A. Pietrewicz, O. Desyatnyk, L. Pszczółkowski, I. Struniewicz, J. Sadlej, J. Chem. Phys. 119, 5907 (2003), doi: 10.1063/1.1602067
  • [6] Z. Kisiel, L. Pszczółkowski, J.C. López, J.L. Alonso, A. Maris, W. Caminati, J. Mol. Spectrosc. 195, 332 (1999), doi: 10.1006/jmsp.1999.7830
  • [7] O. Desyatnyk, L. Pszczółkowski, S. Thorwirth, T.M. Krygowski, Z. Kisiel, Phys. Chem. Chem. Phys. 7, 1708 (2005), doi: 10.1039/B501041A
  • [8] Z. Kisiel, O. Desyatnyk, E. Białkowska-Jaworska, L. Pszczółkowski, Phys. Chem. Chem. Phys. 5, 820 (2003), doi: 10.1039/B212029A
  • [9] G.G. Brown, B.C. Dian, K.O. Douglass, S.M. Geyer, S.T. Shipman, B.H. Pate, Rev. Sci. Instrum. 79, 053103 (2008), doi: 10.1063/1.2919120
  • [10] J.L. Neill, S.T. Shipman, L. Alvarez-Valtierra, A. Lesarri, Z. Kisiel, J. Mol. Spectrosc. 269, 21 (2011), doi: 10.1016/j.jms.2011.04.016
  • [11] C. Pérez, S. Lobsiger, N.A. Seifert, D.P. Zaleski, B. Temelso, G.C. Shields, Z. Kisiel, B.H. Pate, Chem. Phys. Lett. 571, 1 (2013), doi: 10.1016/j.cplett.2013.04.014
  • [12] C. Pérez, M.T. Muckle, D.P. Zaleski, N.A. Seifert, B. Temelso, G.C. Shields, Z. Kisiel, B.H. Pate, Science 336, 897 (2012), doi: 10.1126/science.1220574
  • [13] C. Pérez, D.P. Zaleski, N.A. Seifert, B. Temelso, G.C. Shields, Z. Kisiel, B.H. Pate, Angew. Chem. Int. Ed. 53, 14368 (2014), doi: 10.1002/anie.201407447
  • [14] J.O. Richardson, C. Pérez, S. Lobsiger, A.A. Reid, B. Temelso, G.C. Shields, Z. Kisiel, D.J. Wales, B.H. Pate, S.C. Althorpe, Science 351, 1310 (2016), doi: 10.1126/science.aae0012
  • [15] M.D. Marshall, H.O. Leung, B.Q. Scheertz, J.E. Thaler, J.S. Muenter, J. Mol. Spectrosc. 266, 37 (2011), doi: 10.1016/j.jms.2011.02.005
  • [16] L. Evangelisti, G. Sedo, J. van Wijngaarden, J. Phys. Chem. A 115, 685 (2011), doi: 10.1021/jp1089905
  • [17] G.S. Grubbs II, C.T. Dewberry, K.C. Etchison, K.E. Kerr, S.A. Cooke, Rev. Sci. Instrum. 78, 096106 (2007), doi: 10.1063/1.2786022
  • [18] G.S. Grubbs II, R.A. Powoski, D. Jojola, S.A. Cooke, J. Phys. Chem. A 114, 8009 (2010), doi: 10.1021/jp103966e
  • [19] D.A. Obenchain, A.A. Elliott, A.L. Steber, R.A. Peebles, S.A. Peebles, C.J. Wurrey, G.A. Guirgis, J. Mol. Spectrosc. 261, 35 (2010), doi: 10.1016/j.jms.2010.03.002
  • [20] Z. Kisiel, J. Kosarzewski, B.A. Pietrewicz, L. Pszczółkowski, Chem. Phys. Lett. 325, 523 (2000), doi: 10.1016/S0009-2614(00)00729-6
  • [21] E. Białkowska-Jaworska, L. Pszczółkowski, Z. Kisiel, J. Mol. Spectrosc. 308-309, 20 (2015), doi: 10.1016/j.jms.2014.12.024
  • [22] J. Haeckel, H. Mäder, Z. Nat.forsch. A 43, 203 (1988), doi: 10.1515/zna-1988-0304
  • [23] Z. Kisiel, L. Pszczółkowski, I.R. Medvedev, M. Winnewisser, F.C. De Lucia, E. Herbst, J. Mol. Spectrosc. 233 231 (2005), doi: 10.1016/j.jms.2005.07.006
  • [24] Z. Kisiel, L. Pszczółkowski, B.J. Drouin, C.S. Brauer, S. Yu, J.C. Pearson, I.R. Medvedev, S. Fortman, C. Neese, J. Mol. Spectrosc. 280 134 (2012), doi: 10.1016/j.jms.2012.06.013
  • [25] Z. Kisiel, in: Spectroscopy from Space, Eds. J. Demaison, K. Sarka, E.A. Cohen, Kluwer Academic, Dordrecht 2001, p. 91, doi: 10.1007/978-94-010-0832-7_6
  • [26] Z. Kisiel, PROSPE - Programs for ROtational SPEctroscopy, Institute of Physics, Polish Academy of Sciences, Warsaw
  • [27] M.L. Unland, V. Weiss, W.H. Flygare, J. Chem. Phys. 42 2138 (1965), doi: 10.1063/1.1696257
  • [28] F. Fliege, H. Dreizler, Z. Nat.forsch. A 38, 1231 (1983), doi: 10.1515/zna-1983-1109
  • [29] J.K.G. Watson, in: Vibrational Spectra and Structure, Ed. J.R. Durig, Vol. 6, Elsevier, New York 1977, p. 1, doi: 10.1016/0022-2860(78)87040-9
  • [30] A.A. Granovsky, Firefly version 8 computing package, based on the Gamess-US package, M.W.Schmidt, K.K. Baldridge, J.A. Boatz, S.T. Elbert, M.S. Gordon, J.H. Jensen, S. Koseki, N. Matsunaga, K.A. Nguyen, S. Su, T.L. Windus, M. Dupuis, J.A. Montgomery, J. Comput. Chem. 14, 1347 (1993), doi: 10.1002/jcc.54014111
  • [31] C. Pérez, A.L. Steber, J.C. López, Z. Kisiel, M. Schnell, J. Phys. Chem. Lett. 7, 154 (2016), doi: 10.1021/acs.jpclett.5b02541
  • [32] I. Uriarte, Z. Kisiel, E. Białkowska-Jaworska, L. Pszczółkowski, P. Ecija, F.J. Basterretxea, E.J. Cocinero, J. Mol. Spectrosc., (2017), doi: 10.1016/j.jms.2017.02.011
Document Type
Publication order reference
YADDA identifier
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.