Journal
Article title
Title variants
Languages of publication
Abstracts
Chemical preparation, differential scanning calorimetry and thermal stability differential thermal gravimetry studies, positron annihilation lifetime investigations, optical observations as well as electric properties of the NH₃(CH₂)₃NH₃CuCl₄ crystal are presented. On the basis of the differential scanning calorimetry response the structural phase transition of the first order was observed at 436 K. The enthalpy and entropy of the phase transition are equal to 1120 J/mol and 2.57 J/(mol K), respectively. Differential thermal analysis and thermogravimetric analysis studies confirmed the phase transition at 436 K and one can conclude the chemical and thermal stability of the compound up to about 480 K. Optical observations showed a continuous change of colour from yellow to dark brown above the phase transition to 436 K. Dielectric measurements showed a significant increase of conductivity upon approaching the phase transition regions, with a significant increase above the phase transition temperature. An activation energy dependent on the temperature range, and different for each particular phase, is obtained from measurements of complex impedance.
Discipline
- 78.70.Bj: Positron annihilation(for positron states, see 71.60.+z in electronic structure of bulk materials; for positronium chemistry, see 82.30.Gg in physical chemistry and chemical physics)
- 77.22.Gm: Dielectric loss and relaxation
- 62.20.D-: Elasticity(for materials treatment effects on elastic properties, see 81.40.Jj)
Journal
Year
Volume
Issue
Pages
304-310
Physical description
Dates
published
2017-02
received
2016-12-13
(unknown)
2017-02-11
Contributors
author
- Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland
author
- Department of Physics, Opole University of Technology, Ozimska 75, 45-271 Opole, Poland
author
- Department of Physics, Opole University of Technology, Ozimska 75, 45-271 Opole, Poland
author
- Institute of Experimental Physics, University of Wrocław, Pl. M. Borna 9, 50-204 Wrocław, Poland
author
- Department of Physics, Opole University of Technology, Ozimska 75, 45-271 Opole, Poland
- Institute of Experimental Physics, University of Wrocław, Pl. M. Borna 9, 50-204 Wrocław, Poland
References
- [1] L.P. Battaglia, A. Bonamartini Corradi, G. Pelosi, M.R. Cramarossa, T. Manfredini, G.C. Pellacani, A. Motori, A. Saccani, F. Sandrolini, M.F. Brigatti, Chem. Matter 4, 813 (1992), doi: 10.1021/cm00022a013
- [2] R. Blinc, M. Burgar, B. Lozar, J. Seliger, J. Slak, V. Rutar, H. Arend, R. Kind, J. Chem. Phys. 66, 278 (1977), doi: 10.1063/1.433620
- [3] B. Staśkiewicz, I. Turowska-Tyrk, J. Baran, Cz. Górecki, Z. Czapla, J. Phys. Chem. Solids 75, 1305 (2014), doi: 10.1016/j.jpcs.2014.07.004
- [4] H. Ishihara, Shi-qi Dou, K. Horiuchi, V.G. Krishnan, H. Paulus, H. Fuess, A. Weiss, Z. Naturforsch. a 51, 1216 (1996), doi: 10.1515/zna-1996-1212
- [5] B. Staśkiewicz, O. Czupiński, Z. Czapla, J. Mol. Struct. 1074, 723 (2014), doi: 10.1016/j.molstruc.2014.05.036
- [6] R. Kind, S. Plesko, J. Ross, Phys. Status Solidi A 47, 233 (1978), doi: 10.1002/pssa.2210470127
- [7] D. Phelps, D. Losee, W. Hatfield, D. Hodgson, Inorg. Chem. 15, 3147 (1976), doi: 10.1021/ic50166a042
- [8] M.F. Mostafa, A.A. Youssef, S.S. Montasser, S.S. Khyami, Z. Naturforsch. a 60, 837 (2005), doi: 10.1515/zna-2005-11-1213
- [9] J. Kansy, Nucl. Instrum. Methods Phys. Res. A 374, 235 (1996), doi: 10.1016/0168-9002(96)00075-7
- [10] Z. Czapla, J. Przesławski, M. Crofton, J. Janczak, O. Czupiński, A. Ingram, M. Kostrzewa, Phase Transitions, 1252983 (2016), doi: 10.1080/01411594.2016.1252983
- [11] A. Katrusiak, M. Szafrański, J. Am. Chem. Soc. 128, 15775 (2006), doi: 10.1021/ja0650192
- [12] M. Szafrański, M. Jarek, Cryst. Eng. Commun. 15, 4617 (2013), doi: 10.1039/c3ce26979e
- [13] A.K. Jonscher, Dielectric Relaxation in Solids, Chelsea Dielectric Press, London 1983, p. 340
- [14] R. Krause-Rehberg, H.S. Leipner, Positron Annihilation in Semiconductors. Defect Studies, Springer-Verlag, Berlin 1999, doi: 10.1007/978-3-662-03893-2
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv131n218kz