Magnetic Material Based on Mixed-Valent Dinuclear Pivalate and Cyanidometalate

• Authors: M. Mikuriya , D. Yoshioka , R. Mitsuhashi , D. Luneau , D. Matoga , J. Szklarzewicz , M. Handa
• Languages of publication: EN

Abstracts

EN

Mixed-metal complex consisting of ruthenium(II,III) pivalate, ([Ru₂(piv)₄]⁺) (Hpiv = pivalic acid), tetraethylammonium and octacyanidotungstate(V) ions, (Et₄N)[{Ru₂(piv)₄}₂W(CN)₈]·4H₂O, was synthesized and characterized by elemental analysis, infrared and UV-vis spectra and temperature dependence of magnetic susceptibilities (2-300 K). The magnetic susceptibilities, zero-field-cooled and field-cooled magnetizations, and AC susceptibility data showed that the present complex is ferrimagnetic with T_{c} value of 80 K. The field dependence of magnetization exhibited a hysteresis with a coercive field of 17000 Oe at 5 K.

Keywords

EN

75.30.Et

Discipline

• 75.30.Et: Exchange and superexchange interactions(see also 71.70.Gm Exchange interactions)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2017
• Volume: 131
• Issue: 1
• Pages: 120-123

Dates

published

2017-01

Contributors

author

M. Mikuriya

• Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan

author

D. Yoshioka

• Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan

author

R. Mitsuhashi

• Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan

author

D. Luneau

• Laboratoire des Multimatériaux et Interfaces, Université Claude Bernard Lyon 1, Campus de La Doua, 69622 Villeurbanne Cedex, France

author

D. Matoga

• Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan

author

J. Szklarzewicz

• Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060 Krakow, Poland

author

M. Handa

• Shimane University, Interdisciplinary Graduate School of Science and Engineering, 1060 Nishikawatsu, Matsue 669-8504, Japan

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Identifiers

DOI

10.12693/APhysPolA.131.120