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2017 | 131 | 1 | 120-123
Article title

Magnetic Material Based on Mixed-Valent Dinuclear Pivalate and Cyanidometalate

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EN
Abstracts
EN
Mixed-metal complex consisting of ruthenium(II,III) pivalate, ([Ru₂(piv)₄]⁺) (Hpiv = pivalic acid), tetraethylammonium and octacyanidotungstate(V) ions, (Et₄N)[{Ru₂(piv)₄}₂W(CN)₈]·4H₂O, was synthesized and characterized by elemental analysis, infrared and UV-vis spectra and temperature dependence of magnetic susceptibilities (2-300 K). The magnetic susceptibilities, zero-field-cooled and field-cooled magnetizations, and AC susceptibility data showed that the present complex is ferrimagnetic with T_{c} value of 80 K. The field dependence of magnetization exhibited a hysteresis with a coercive field of 17000 Oe at 5 K.
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EN
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Year
Volume
131
Issue
1
Pages
120-123
Physical description
Dates
published
2017-01
Contributors
author
  • Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan
author
  • Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan
author
  • Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan
author
  • Laboratoire des Multimatériaux et Interfaces, Université Claude Bernard Lyon 1, Campus de La Doua, 69622 Villeurbanne Cedex, France
author
  • Kwansei Gakuin University, School of Science and Technology, 2-1 Gakuen, Sanda 669-1337, Japan
  • Faculty of Chemistry, Jagiellonian University, R. Ingardena 3, 30-060 Krakow, Poland
author
  • Shimane University, Interdisciplinary Graduate School of Science and Engineering, 1060 Nishikawatsu, Matsue 669-8504, Japan
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv131n134kz
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