The Influence of Selected Organic Compounds on the Corrosion of Historical Glass Based on Their State of Preservation

• Authors: E. Greiner-Wronowa , P. Świt
• Languages of publication: EN

Abstracts

EN

The aim of this study was to investigate the influence of selected organic compounds such as acetic acid and formaldehyde on the historical glass objects of corrosion processes. This is a very important problem for the field of conservation and restoration of glass of art. Glass objects exhibited in museum display cases can be suffered by evaporating organic compounds which undergo to reaction with leached glass elements to create corrosion deposit on their surface. The proposed method called glass sensors has been used to identify results of impact of various external factors on the tested glass. Due to aggressive environment for the objects there created corrosion phenomena. Glass sensor were prepared as reproduced XVIII-cent. materials. The current studies were carried out by modern physico-chemical methods such as optical, metallography, scanning electron microscopy, inductively coupled plasma mass spectrometry and the Fourier transform infrared spectrometry. These techniques allow to determine the composition of the corrosion layers as well as their structure. The issues raised in this work have been studied following an interdisciplinary approach. The information obtained by using different techniques provides a valuable source of knowledge about the chemical reactions taking place on the surface of the glass. The results derived from this work are useful for the design and implementation of exhibition recommendations and better planning of conservation tasks.

Keywords

EN

89.90.+n; 61.43.Fs; 07.60.Pb; 68.37.-d; 68.37.Hk; 81.70.-q; 07.07.Df; 07.75.+h; 81.40.Np

Discipline

• 81.40.Np: Fatigue, corrosion fatigue, embrittlement, cracking, fracture, and failure(see also 62.20.M- Structural failure of materials)
• 07.60.Pb: Conventional optical microscopes(for near-field scanning optical microscopes, see 07.79.Fc; for x-ray microscopes, see 07.85.Tt)
• 07.07.Df: Sensors (chemical, optical, electrical, movement, gas, etc.); remote sensing
• 07.75.+h: Mass spectrometers(see also 82.80.Ms, 82.80.Nj, and 82.80.Rt in physical chemistry and chemical physics)
• 68.37.Hk: Scanning electron microscopy (SEM) (including EBIC)
• 68.37.-d: Microscopy of surfaces, interfaces, and thin films
• 89.90.+n: Other topics in areas of applied and interdisciplinary physics (restricted to new topics in section 89)
• 61.43.Fs: Glasses
• 81.70.-q: Methods of materials testing and analysis(see also 82.80.-d Chemical analysis and related physical methods of analysis)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 130
• Issue: 6
• Pages: 1406-1414

Dates

published

2016-12

received

2016-01-12

Contributors

author

E. Greiner-Wronowa

• AGH University of Science and Technology, Faculty of Materials Science and Ceramics, Department of Glass Technology and Amorphous Coatings, A. Mickiewicza 30, 30-059 Kraków, Poland

author

P. Świt

• Jagiellonian University, Faculty of Chemistry, Department of Analytical Chemistry, R. Ingardena 3, 30-060 Krakow, Poland

References

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Identifiers

DOI

10.12693/APhysPolA.130.1406