Optical Nonlinearity Investigation of the Novel Organic-Inorganic Hybrid Salt: 1,1'-methylenedipyridinium pentacynidonitrosoferrate(II)pentahydrate Using Z-Scan System

• Authors: M.D. Zidan , M. Al-Ktaifani , A. Allahham
• Languages of publication: EN

Abstracts

EN

The organic-inorganic hybrid salt: 1,1'-methylenedipyridinium pentacynidonitrosoferrate(II)pentahydrate is synthesized and characterized by multinuclear NMR, IR, and UV-vis spectroscopies and elemental analysis. The third order nonlinear optical properties of the new complex in an aqueous solution have been studied using Z-scan technique. Measurements were performed for input intensities (I₀) of 437 and 241 W/cm² for the two concentrations with a CW diode laser at 635 nm wavelength. The nonlinear optical absorption coefficient (β) and nonlinear refraction (n₂) are found at 1.28×10¯³ cm/W and 10.17×10¯⁹ cm²/W, respectively. The overall results suggested that better nonlinearity was observed at a higher concentration of sample. Our results suggest that this material is considered as a promising candidate for future optical device applications.

Keywords

EN

42.65.Ky; 42.70.Nq; 42.70.Jk; 84.30.Qi

Discipline

• 84.30.Qi: Modulators and demodulators; discriminators, comparators, mixers, limiters, and compressors
• 42.70.Jk: Polymers and organics
• 42.65.Ky: Frequency conversion; harmonic generation, including higher-order harmonic generation(see also 42.79.Nv Optical frequency converters)
• 42.70.Nq: Other nonlinear optical materials; photorefractive and semiconductor materials

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 130
• Issue: 6
• Pages: 1326-1331

Dates

published

2016-12

received

2015-08-30

(unknown)

2016-03-14

(unknown)

2016-11-03

Contributors

author

M.D. Zidan

• Department of Physics, Atomic Energy Commission, P.O. Box 6091, Damascus, Syria

author

M. Al-Ktaifani

• Department of Radioisotopes, Atomic Energy Commission, P.O. Box 6091, Damascus, Syria

author

A. Allahham

• Department of Physics, Atomic Energy Commission, P.O. Box 6091, Damascus, Syria

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Identifiers

DOI

10.12693/APhysPolA.130.1326