An EPR Study on Radiation-Induced 2-(piperidin-1-ylmethyl)phenol Single Crystal

• Authors: K. Usta , Y. Ceylan , A. Usta , N. Ceylan , E. Aras
• Languages of publication: EN

Abstracts

EN

For the assessment of irradiation influence on 2-(piperidin-1-ylmethyl)phenol single crystals (C₁₂H₁₇NO), electron paramagnetic resonance measurements were carried out on the samples exposed to ⁶⁰Co radiation at dose values of 22.8, 45.6 and 68.4 kGy at room temperature. Electron paramagnetic resonance signals were not observed in non-irradiated sample and in samples irradiated at dose values of 22.8 and 45.6 kGy. The electron paramagnetic resonance measurements were performed on the single crystals. This irradiated single crystal was rotated in steps of 10°. One type of radical center was found. The average values of g and hyperfine constant of the detected radiation damage center were calculated from experimental spectra as follows: g=2.0052, A_{H} = 0.74 mT.

Keywords

EN

87.66.Uv; 36.20.Kd; 39.30.+w; 33.35.+r

Discipline

• 36.20.Kd: Electronic structure and spectra
• 33.35.+r: Electron resonance and relaxation(see also 76.30.-v Electron paramagnetic resonance and relaxation in condensed matter)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 130
• Issue: 1
• Pages: 178-180

Dates

published

2016-07

Contributors

author

K. Usta

• Alanya Alaaddin Keykubat University, Department of Metallurgical and Materials Engineering, Antalya, Turkey

author

Y. Ceylan

• Selcuk University, Department of Physics, Konya, Turkey

author

A. Usta

• Alanya Alaaddin Keykubat University, Department of Mechanical Engineering, Antalya, Turkey

author

N. Ceylan

• Giresun University, Department of Chemistry, Giresun, Turkey

author

E. Aras

• Gazi University, Department of Physics, Ankara, Turkey

References

• [1] S.H. Lin, R.S. Juang, J. Environ. Manag. 90, 1336 (2009)
• [2] J Paca Jr, V. Kremlackova, M. Turek, V. Sucha, L. Vilimkova, J. Paca, M Halecky, Enzyme Microb. Tech. 40, 919 (2007), doi: 10.1016/j.enzmictec.2006.07.028
• [3] C. Zidi, R. Tayeb, M.B. Sik Ali, M. Dhahbi, J. Membrane Sci. 360, 334 (2010), doi: 10.1016/j.memsci.2010.05.027
• [4] J.B. Kowalski, A.S. Yan, A. Tallentire, Radiat. Phys. Chem. 58, 77 (2000), doi: 10.1016/S0969-806X(99)00354-0
• [5] J.B. Kowalski, C. Herring, L. Baryschpolec, Radiat. Phys. Chem. 64, 411 (2002), doi: 10.1016/S0969-806X(01)00681-8
• [6] D. Boxue, G. Yu, Polymer Deg. Stab. 94, 139 (2009), doi: 10.1016/j.polymdegradstab.2008.08.009
• [7] E. Aras, B. Asik, B. Caliskan, M. Buyum, M. Birey, Radiat. Effect. Def. Solid, 159, 353 (2004), doi: 10.1080/10420150410001731820
• [8] A. Usta, H. Cingilli Vural, K. Usta, E. Aras, Y. Ceylan, A. Ozmen, J. Phys. Org. Chem. 24, 635 (2011), doi: 10.1002/poc.1801
• [9] Y. Ceylan, K. Usta, A. Usta, H. Yumurtaci Aydogmus, A. Guner, J. Mol. Struct. 1100, 180 (2015), doi: 10.1016/j.molstruc.2015.07.022
• [10] M.J. Lopez-Munoz, J. Soria, J.C. Conesa, V. Augugliaro, Stud. Surf. Sci. Catal. 82, 693 (1994), doi: 10.1016/S0167-2991(08)63465-5

Identifiers

DOI

10.12693/APhysPolA.130.178