Thermal Decomposition Behaviour of Bis(4-Nitrophenol)-2,4,6-Triamino-1,3,5-Triazine Monohydrate

• Authors: N. Kanagathara , M. Marchewka , G. Anbalagan
• Languages of publication: EN

Abstracts

EN

Thermal decomposition behavior of bis (4-nitrophenol)-2,4,6-triamino-1,3,5-triazine monohydrate (BNPM) has been studied by means of thermogravimetric analysis at three different heating rates 10, 15 and 20°C min¯¹. Non-isothermal studies of BNPM have revealed that the decomposition occurs in three stages involving dehydration and decomposition. The values of effective activation energy (E_{a}), pre-exponential factor (A) of each stage of thermal decomposition for all heating rates were calculated by model free methods: Arrhenius, Flynn-Wall, Friedman, Kissinger and Kim-Park method. A significant variation of effective activation energy (E_{a}) with conversion (α) indicates that the process is kinetically complex. The linear relationship between the A and E_{a} values was well established (compensation effect). Dehydration stage was governed by the Avrami-Erofeev model (A2) and decomposition stages were governed by the Avrami-Erofeev model (A4).

Keywords

EN

83.60.St; 87.15.R-; 91.60.Ki; 82.20.Pm

Discipline

• 87.15.R-: Reactions and kinetics(see also 82.39.-k Chemical kinetics in biological systems in physical chemistry)
• 83.60.St: Non-isothermal rheology
• 82.20.Pm: Rate constants, reaction cross sections, and activation energies
• 91.60.Ki: Thermal properties

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 129
• Issue: 6
• Pages: 1235-1241

Dates

published

2016-06

received

2015-10-12

(unknown)

2016-05-02

Contributors

author

N. Kanagathara

• School of Basic Sciences, Vel Tech University, Chennai-62, India

author

M. Marchewka

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 937, 50-950 Wrocław 2, Poland

author

G. Anbalagan

• Department of Nuclear Physics University of Madras Guindy Campus Chennai-600025

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Identifiers

DOI

10.12693/APhysPolA.129.1235