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2016 | 129 | 6 | 1235-1241
Article title

Thermal Decomposition Behaviour of Bis(4-Nitrophenol)-2,4,6-Triamino-1,3,5-Triazine Monohydrate

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EN
Thermal decomposition behavior of bis (4-nitrophenol)-2,4,6-triamino-1,3,5-triazine monohydrate (BNPM) has been studied by means of thermogravimetric analysis at three different heating rates 10, 15 and 20°C min¯¹. Non-isothermal studies of BNPM have revealed that the decomposition occurs in three stages involving dehydration and decomposition. The values of effective activation energy (E_{a}), pre-exponential factor (A) of each stage of thermal decomposition for all heating rates were calculated by model free methods: Arrhenius, Flynn-Wall, Friedman, Kissinger and Kim-Park method. A significant variation of effective activation energy (E_{a}) with conversion (α) indicates that the process is kinetically complex. The linear relationship between the A and E_{a} values was well established (compensation effect). Dehydration stage was governed by the Avrami-Erofeev model (A2) and decomposition stages were governed by the Avrami-Erofeev model (A4).
Keywords
Contributors
  • School of Basic Sciences, Vel Tech University, Chennai-62, India
author
  • Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 937, 50-950 Wrocław 2, Poland
author
  • Department of Nuclear Physics University of Madras Guindy Campus Chennai-600025
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Document Type
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv129n631kz
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