Evaluation of Surface Characteristics and Physical Properties on Biodegradable Magnesium-Calcium Alloys by Anodic Oxidation

• Authors: J. Kim , J. Lee , H. Yang , S. Park , H. Lim , G. Oh , K. Yun
• Languages of publication: EN

Abstracts

EN

The purpose of this study was to determine the effect of calcium (Ca) on the surface characteristics and physical properties of magnesium-calcium alloys after anodization. A novel binary alloy Mg-xCa (in which x=0.5, 1, or 5 wt.%) was cast by combining magnesium (99.9%) and calcium (99.9%) in an argon gas (99.99%) atmosphere. A magnesium alloy rod having a diameter of 15 mm was cut into discs, each 2 mm thick. The specimens were subjected to anodic oxidation at 120 V for 15 minutes at room temperature in an electrolyte solution consisting of calcium gluconate, sodium hexametaphosphate, and sodium hydroxide. Surface and cross-sectional morphological changes were observed using scanning electron microscopy, and the microstructures and phases were detected by means of X-ray diffraction. Hardness and surface roughness were assessed by means of a Vickers hardness tester and a surface roughness meter, respectively. The results show that the physical properties of these magnesium-calcium alloys have been improved, because it was possible to control the dissolution rate according to the amount of calcium added.

Keywords

EN

87.85.jj; 87.85.jc

Discipline

• 87.85.jc: Electrical, thermal, and mechanical properties of biological matter
• 87.85.jj: Biocompatibility

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 129
• Issue: 4
• Pages: 736-741

Dates

published

2016-04

Contributors

author

J. Kim

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea

author

J. Lee

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea
• Seoul Narin Dental Clinic, 62247 Gwangju, Republic of Korea

author

H. Yang

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea

author

S. Park

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea

author

H. Lim

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea

author

G. Oh

• Chonnam National University, RIS Foundation for Advanced Biomaterials, 61186 Gwangju, Republic of Korea

author

K. Yun

• Chonnam National University, School of Dentistry, 61186 Gwangju, Republic of Korea

References

• [1] H.K. Seok, Y.C. Kim, P.R. Cha, G.S. Han, Y.Y. Kim, S.Y. Cho, S.J. Yang, Korean J. Met. Mater. 22, 29 (2009)
• [2] Y. Song, S. Zhang, J. Li, C. Zhao, X. Zhang, Acta Biomater. 6, 1736 (2010), doi: 10.1016/j.actbio.2009.12.020
• [3] H.G. Seiler, H. Sigel, A. Sigel, Handbook on Toxicity of Inorganic Compounds, Marcel Dekker 1988
• [4] R.J. Elin, Clin. Chem. 33, 1965 (1987)
• [5] H. Zreiqat, C.R. Howlett, A. Zannettino, P. Evans, G. Schulze-Tanzil, C. Knabe, M. Shakibaei, J. Biomed. Mater. Res. 62, 175 (2002), doi: 10.1002/jbm.10270
• [6] M.P. Staiger, A.M. Pietak, J. Huadmai, G. Dias, Biomaterials 27, 1728 (2006), doi: 10.1016/j.biomaterials.2005.10.003
• [7] E.P.D. Garmo, J.T. Black, R.A. Kohser, DeGarmo's Materials and Processes in Manufacturing, John Wiley & Sons 2011
• [8] L. J. Gibson, M.F. Ashby, Cellular Solids: Structure and Properties, Cambridge University Press 1997
• [9] J.W. Choi, Y.M. Kong, H.E. Kim, I.S. Lee, J. Am. Ceram. Soc. 81, 1743 (1998)
• [10] T.V. Thamaraiselvi, S. Rajeswari, Trends Biomater. Artif. Organs. 18, 9 (2004)
• [11] F. Witte, V. Kaese, H. Haferkamp, E. Switzer, A. Meyer-Lindenberg, C.J. Wirth, H. Windhagen, Biomaterials 26, 3557 (2005), doi: 10.1016/j.biomaterials.2004.09.049
• [12] C.E. Wen, M. Mabuchi, Y. Yamada, K. Shimojima, Y. Chino, T. Asahina, Scr. Mater. 45, 1147 (2001), doi: 10.1016/S1359-6462(01)01132-0
• [13] H. Wang, Z.M. Shi, K. Yang, Adv. Mater. Res. 32, 207 (2008), doi: 10.4028/www.scientific.net/AMR.32.207
• [14] H.Y. López, D.A. Cortés-Hernández, S. Escobedo, D. Mantovani, Key Engin. Mater. 309, 453 (2006), doi: 10.4028/www.scientific.net/KEM.309-311.453
• [15] J.H. Ji, Y.K. Kim, I.S. Park, H.H. Park, T.S. Bae, M.H. Lee, Korean Soc. Dent. Mater. 39, 26 (2012)
• [16] R.B. Figueiredo, T.G. Langdon, J. Mater. Sci. 44, 4758 (2009), doi: 10.1007/s10853-009-3725-z
• [17] C.C. Koch, R.O. Scattergood, K.M. Youssef, E. Chan, Y.T. Zhu, J. Mater. Sci. 45, 4725 (2010), doi: 10.1007/s10853-010-4252-7
• [18] B. Denkena, F. Witte, C. Podolsky, A. Lucas, Proc. 5th Euspen Int., 2005, p. 233
• [19] S.G. Lee, Ph.D. Thesis, Pusan National University, 2012
• [20] Z. Li, X. Gu, S. Lou, Y. Zheng, Biomaterials 29, 1329 (2008), doi: 10.1016/j.biomaterials.2007.12.021
• [21] S.G. Steinemann, Corrosion of Surgical Implants - in Vivo and in Vitro Tests, John Wiley & Sons, 1980
• [22] Y. Okazaki, S. Rao, T. Tateishi, Y. Ito, Mater. Sci. Eng. A 243, 250 (1998), doi: 10.1016/S0921-5093(97)00809-5
• [23] K. Feser, M. Kietzmann, W. Baumer, C. Krause, F.W. Bach, J. Biomater. Appl. 25, 685 (2011), doi: 10.1177/0885328209360424
• [24] A. Krause, N. von der Höh, D. Bormann, C. Krause, F.W. Bach, H. Windhagen, A. Meyer-Lindenberg,J. Mater. Sci. Mater. Med. 45, 624 (2010), doi: 10.1007/s10853-009-3936-3
• [25] F. Witte, Acta Biomater. 6, 1680 (2010), doi: 10.1016/j.actbio.2010.02.028
• [26] A. Zakiyuddin, M.Sc. Thesis, Chonnam National University, 2014
• [27] N.T. Kirkland, N. Birbilis, M.P. Staiger, Acta Biomater. 8, 925 (2012), doi: 10.1016/j.actbio.2011.11.014
• [28] C. Lorenz, J.G. Brunner, P. Kollmannsberger, L. Jaafar, B. Fabry, S. Virtanen, Acta Biomater. 5, 2783 (2009), doi: 10.1016/j.actbio.2009.04.018
• [29] K.J. Park, M.W. Jung, J.H. Lee, J. Microelectronics Packaging Soc. 17, 71 (2010)
• [30] M.H. Kim, Ph.D. Thesis, Pukyong National University, 2010
• [31] D.K. Lee, M.Sc. Thesis, Pusan National University, 2010
• [32] P.B. Srinivasan, C. Blawert, W. Dietzel, Mater. Sci. Eng. A 494, 401 (2008), doi: 10.1016/j.msea.2008.04.031
• [33] Y. Zhang, C. Yan, F. Wang, H. Lou, C. Cao, Surf. Coat. Technol. 161, 36 (2002), doi: 10.1016/S0257-8972(02)00342-0
• [34] H. Duan, K. Du, C. Yan, F. Wang, Electrochim. Acta. 51, 2898 (2006), doi: 10.1016/j.electacta.2005.08.026
• [35] R. Kartika, M.Sc. Thesis, Yeungnam University, 2007
• [36] Q. Zhao, X. Guo, X. Dang, J. Hao, J. Lai, K. Wang, Colloids Surf. B. Biointerfaces 102, 321 (2013), doi: 10.1016/j.colsurfb.2012.07.040
• [37] A.Y. Kim, Ph.D. Thesis, Chonnam National University, 2014
• [38] B.H. Kim, Ph.D. Thesis, Pusan National University, 2012
• [39] J.C. Oh, T. Ohkubo, T. Mukai, K. Hono, Scr. Mater. 53, 675 (2005), doi: 10.1016/j.scriptamat.2005.05.030
• [40] K.I. Kim, Ph.D. Thesis, Chonbuk National University, 2013

Identifiers

DOI

10.12693/APhysPolA.129.736