Synthesis and Characterization of a Water-Soluble Ionic Polyacetylene Derivative

Gal, Y.; Jin, S.; Park, J.; Lim, K.

doi:10.12693/APhysPolA.129.642

Journal

Acta Physica Polonica A

2016 | 129 | 4 | 642-646

Article title

Synthesis and Characterization of a Water-Soluble Ionic Polyacetylene Derivative

Authors

Y. Gal , S. Jin , J. Park , K. Lim

Content

Full texts:

http://przyrbwn.icm.edu.pl/APP/PDF/129/a129z4p058.pdf [remote]

Title variants

Languages of publication

Abstracts

A new water-soluble ionic polyacetylene was synthesized by the acid-catalyzed polymerization of 2-ethynylpyridine using acrylic acid. The polymerization proceeded well to give a high yield of polymer. The acetylenic C ≡ C bond stretching (2110 cm¯¹) and acetylenic ≡ C-H bond stretching (3293 cm¯¹) peaks of 2-ethynylpyridine monomer were not seen in the FT-IR spectrum of polymer. The electro-optical and electrical properties of the ionic polyacetylene were measured and discussed. The resulting polymer showed strong maximum at 513 nm in the UV-Visible absorption, which is corresponding to photon energy of 2.42 eV. The energy gap width of polymer was estimated to be of 2.08 eV. It was observed that the electrochemical process of polymer is reproducible in the potential range of -1.80 to 1.60 V vs Ag/AgNO₃. HOMO and LUMO levels of polymer were 4.85 eV and 2.77 eV, respectively.

Keywords

72.80.L 73.61.P 78.20.C 78.30.J

Publisher

Institute of Physics, Polish Academy of Sciences

Journal

Acta Physica Polonica A

Year

2016

Volume

129

Issue

Pages

642-646

Physical description

Dates

published

2016-04

Contributors

author

Y. Gal

Department of Fire Safety, Kyungil University, Gyeongsan 38428, Gyeongsangbuk-do, Korea

author

S. Jin

Department of Chemistry Education, Pusan National University, Busan 46279, Korea

author

J. Park

Department of Chemistry, The Catholic University of Korea, Bucheon 14662, Korea

author

K. Lim

Department of Display Engineering, Pukyong National University, Busan 48513, Korea

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Document Type

Publication order reference

Identifiers

DOI

10.12693/APhysPolA.129.642

YADDA identifier

bwmeta1.element.bwnjournal-article-appv129n4058kz