Fabrication and Characterization of AgNPs Incorporated PVA/ODA-MMT and PVP/ODA-MMT Nanofiber Structures by Green Electrospinning Nanotechnology as Excellent Conducting and Bioengineering Nanomaterial

• Authors: U. Bunyatova , Z. Rzayev , İ. Koçum , M. Şimşek , M. Yürüksoy
• Languages of publication: EN

Abstracts

EN

This work presents synthesis and characterization of novel nanofiber structures from the pure water solution blends of poly(vinyl alcohol, hydrolyzed 89%) (PVA/octadecylamine-montmorillonite (ODA-MMT, 5 mass%) as a matrix and poly(N-vinylpyrrolidone) (PVP)/ODA-MMT (5 mass%) as a partner preintercalated nanocomposites and their AgNPs incorporated derivatives by green electrospinning nanotechnology. The chemical and physical structures, surface morphologies, and conductivities were investigated by the Fourier transform infrared, X-ray diffraction, scanning electron microscopy, conducting analysis methods. The fabricated multifunctional nanofibers predominantly exhibit colloidal-like amorphous structures, which is an important factor to improve tendency to self-assembly and therefore, the conductivities of the nanofiber polyelectrolyte structures. Obtained morphologies of composite nanofibers show cross-section structures with fine diameter distribution with higher contact areas. The nanofiber composites show excellent electrical conductivity at temperature range of 20-45°C. The obtained unique properties of multifunctional nanofiber surfaces with higher contact areas can be used for wide applications in microelectronics, sensor devices, nanolithography (X-ray, E-beam and photoresists), electrochemical (surface functionalized electrods) and bioengineering processing.

Keywords

EN

81.07.-b

Discipline

• 81.07.-b: Nanoscale materials and structures: fabrication and characterization(for structure of nanoscale materials, see 61.46.-w; for nanostructured materials in electrochemistry, see 82.45.Yz; see also 62.23.-c Structural classes of nanoscale systems in mechanical properties of condensed matter)

• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 129
• Issue: 4
• Pages: 431-435

Dates

published

2016-04

Contributors

author

U. Bunyatova

• Department of Biomedical Engineering, Faculty of Engineering, Baskent University, 06810 Ankara, Turkey

author

Z. Rzayev

• Institute of Science and Engineering, Division of Nanotechnology and Nanomedicine, Hacettepe University, Beytepe, 06800 Ankara, Turkey

author

İ. Koçum

• Department of Biomedical Engineering, Faculty of Engineering, Baskent University, 06810 Ankara, Turkey

author

M. Şimşek

• Institute of Science and Engineering, Division of Nanotechnology and Nanomedicine, Hacettepe University, Beytepe, 06800 Ankara, Turkey

author

M. Yürüksoy

• Department of Biomedical Engineering, Faculty of Engineering, Baskent University, 06810 Ankara, Turkey

References

• [1] P. Taepaiboon, U. Rundsardthong, P. Supaphol, Nanotechnology 17, 2317 (2006), doi: 10.1088/0957-4484/17/9/041
• [2] M. Jannesari, J. Varshosaz, M. Morshed, M. Zamani, Int. J. Nanomed. 6, 993 (2011), doi: 10.2147/IJN.S17595
• [3] K.E. Strawhecker, E. Manias, Chem. Mater. 12, 2943 (2000), doi: 10.1021/cm000506g
• [4] J.-H. Chang, T.-G. Jang, K.J. Ihn, W.-K. Lee, G.S. Sur, J. Appl. Polym. Sci. 90, 3208 (2002), doi: 10.1002/app.12996
• [5] T. Galya, V. Sedlarik, I. Novotny, J. Sedlarkova, P. Saha, J. Appl. Polym. Sci. 110, 3178 (2008), doi: 10.1002/app.28908
• [6] N. Mahanta, Y. Teow, S. Valiyaveettil, J. Nanosci. Nanotechnol. 12, 6156 (2012), doi: 10.1002/app.28908
• [7] U.R. Salamova, A.A. Masimov, M. Ozer, Polymer 37, 2191 (1996), doi: 10.1016/0032-3861(96)85864-2
• [8] U.R. Salamova, Z.M.O. Rzaev, S. Altindal, A.A. Masimov, Polymer 37, 2415 (1996), doi: 10.1016/0032-3861(96)85353-5
• [9] D.-G. Yu, K. White, J.-H. Yang, X. Wang, W. Gian, Y. Li, Mater. Lett. 67, 78 (2012), doi: 10.1016/j.matlet.2011.09.035
• [10] D.H. Reneker, I. Chun, Nanotechnology 7, 216 (1996), doi: 10.1088/0957-4484/7/3/009
• [11] W.E. Teo, S. Ramakrishna, Nanotechnology 17, 89 (2006), doi: 10.1088/0957-4484/17/14/R01
• [12] K. Graham, G.H. Schreuder, M. Gogins, in: Proc. Int. Nonwoven Technical Conf., Technical Association of the Pulp & Paper Industry, Baltimore (USA) 2003, p. 15 http://thefutureisnear.org/student_research/current_research/documents/filtration/050271(Filtration).pdf
• [13] K.H. Hong, Polym. Eng. Sci. 47, 43 (2007), doi: 10.1002/pen.20660
• [14] In series: Advances in Polymer Science v. 246, Eds. R. Jayakumar, S.V. Nair, V. Beachley, Springer-Verlag, Heidelberg 2012, p. 263
• [15] B. Gupta, R. Agarwal, M.S. Alam, Indian J. Fibers Textile Res. 35, 174 (2010) http://nopr.niscair.res.in/handle/123456789/9766
• [16] G. Inzelt, M. Pineri, J.W. Schultze, M.A. Vorotyntsev, Electrochim. Acta 45, 2403 (2000), doi: 10.1016/S0013-4686(00)00329-7
• [17] F.F. Hatta, M.Z.A. Yahya, A.M.M. Ali, R.H.Y. Subban, M.K. Harun, A.A. Mohamad, Ionics 11, 418 (2005), doi: 10.1007/BF02430259
• [18] N. Rajeswari, S. Selvasekarapandian, S. Karthikeyan, M. Prabu, G. Hirankumar, H. Nithya, C. Sanjeeviraja, J. Non-Cryst. Solids 357, 3751 (2011), doi: 10.1016/j.jnoncrysol.2011.07.037
• [19] W.S. Khan, R. Asmatulu, M.M. Eltabey, J. Nanomater. 2013, 160391 (2013), doi: 10.1155/2013/160931
• [20] W.S. Khan, Ph.D. Thesis, Wichita State University, Wichita, Kan, USA (2010)
• [21] L. Wang, L. Zhang, M. Tian, Polym. Adv. Technol. 23, 652 (2012), doi: 10.1002/pat.1940
• [22] M. Naebe, T. Lin, M.P. Staiger, L. Dai, X. Wang, Nanotechnology 19, 30 (2008), doi: 10.1088/0957-4484/19/30/305702

Identifiers

DOI

10.12693/APhysPolA.129.431