Novel Metal(II) Complexes with Bidentate Schiff Base Ligand: Synthesis, Spectroscopic Properties and Dye Decolorization Functions

• Authors: C. Karakaya , B. Dede , E. Cicek
• Languages of publication: EN

Abstracts

EN

The bidentate Schiff base ligand 4-chloro-2-[1-(4-phenylphenyl)ethylideneamino]phenol and its mononuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized. Ligand and metal complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, ¹H- and ¹³C-NMR, the Fourier transform infrared, UV-Vis, inductively coupled plasma optical emission spectrometry, and thermogravimetric-differential thermogravimetric studies. The results suggest that the mononuclear complexes have a metal to ligand mole ratio of 1:2 and the metal(II) ions are coordinated with the phenolic oxygen and imine nitrogen atoms. Octahedral structures are proposed for the complexes of the Schiff base ligand. Furthermore, the complexes were checked for their efficiency to decolorize the dye methylene blue. In our experiments we found that metal(II) complexes had an acceptable decolorization efficiency against the dye methylene blue.

Keywords

EN

81.20.Ka; 82.80.-d; 89.60.-k

Discipline

• 82.80.-d: Chemical analysis and related physical methods of analysis(for related instrumentation, see section 07; for spectroscopic techniques in biological physics, see 87.64.-t)
• 89.60.-k: Environmental studies(for ecology, see 87.23.-n; for environmental impacts of renewable energy, see 88.05.Np)
• 81.20.Ka: Chemical synthesis; combustion synthesis(for electrochemical synthesis, see 82.45.Aa)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2016
• Volume: 129
• Issue: 2
• Pages: 208-212

Dates

published

2016-02

Contributors

author

C. Karakaya

• Faculty of Engineering, Celal Bayar University, Manisa, Turkey

author

B. Dede

• Faculty of Science and Art, Süleyman Demirel University, Isparta, Turkey

author

E. Cicek

• Faculty of Science and Art, Mehmet Akif Ersoy University, Burdur, Turkey

References

• [1] M. Negoiu, S. Pasculescu, T. Rosu, R. Georgescu, C. Draghici, Rev. Chim. (Bucharest) 61, 762 (2010)
• [2] A. Nishinaga, T. Yamada, H. Fujisawa, K. Ishizaki, H. Ihara, T. Matsuura, J. Mol. Catal. 48, 249 (1988), doi: 10.1016/0304-5102(88)85009-0
• [3] Y. Hamada, IEEE Trans. Electron Devices 44, 1208 (1997, doi: 10.1109/16.605456
• [4] A.I. Hanafy, A.K.T. Maki, M.M. Mostafa, Transition Met. Chem. 32, 960 (2007), doi: 10.1007/s11243-007-0268-5
• [5] I. Arslan, I.A. Balcioglu, T. Tuhkanen, D. Bahnemann, J. Environ. Eng. 126, 903 (2000), doi: 10.1061/(ASCE)0733-9372(2000)126:10(903)
• [6] S.K. Chaudhuri, B. Sur, J. Environ. Eng. 126, 583 (2000), doi: 10.1061/(ASCE)0733-9372(2000)126:7(583)
• [7] N. Levin, W.H. Hartung, J. Org. Chem. 7, 408 (1942), doi: 10.1021/jo01199a002
• [8] M. Gaber, M.M. Ayad, Y.S.Y. El-Sayed, Spectrochim. Acta, Part A 62, 694 (2005), doi: 10.1016/j.saa.2005.02.039
• [9] N.M. Shauib, A.A. Elassar, A. El-Dissouky, Spectrochim. Acta, Part A 63, 714 (2006), doi: 10.1016/j.saa.2005.06.024
• [10] G. Das, R. Shukla, S. Mandal, R. Singh, P.K. Bharadwaj, J. van Hall, K.H. Whitmire, Inorg. Chem. 36, 323 (1997), doi: 10.1021/ic9510371
• [11] C.A. McAuliffe, R.V. Parish, F.M. Ashmawy, R.M. Issa, S.A. Amer, J. Chem. Soc. Dalton Trans. 1987, 2009 (1987), doi: 10.1039/DT9870002009
• [12] I.A. Kahwa, J. Selbin, T.C.Y. Hsieh, R.A. Laine, Inorg. Chim. Acta 118, 179 (1986), doi: 10.1016/S0020-1693(00)81385-7
• [13] M.M.H. Khalil, M.M.Mashaly, Chin. J. Chem. 26, 1669 (2008), doi: 10.1002/cjoc.200890302
• [14] W.J. Geary, Coord. Chem. Rev. 7, 81 (1971), doi: 10.1016/S0010-8545(00)80009-0
• [15] F. Magalhaes, F.C.C. Moura, J.D. Ardisson, R.M. Lago, Mater. Res. 11, 307 (2008, doi: 10.1590/S1516-14392008000300013

Identifiers

DOI

10.12693/APhysPolA.129.208