PL EN


Preferences help
enabled [disable] Abstract
Number of results
2016 | 129 | 2 | 208-212
Article title

Novel Metal(II) Complexes with Bidentate Schiff Base Ligand: Synthesis, Spectroscopic Properties and Dye Decolorization Functions

Content
Title variants
Languages of publication
EN
Abstracts
EN
The bidentate Schiff base ligand 4-chloro-2-[1-(4-phenylphenyl)ethylideneamino]phenol and its mononuclear Co(II), Ni(II), Cu(II) and Zn(II) complexes have been synthesized. Ligand and metal complexes were characterized by elemental analyses, magnetic susceptibility, molar conductivity, ¹H- and ¹³C-NMR, the Fourier transform infrared, UV-Vis, inductively coupled plasma optical emission spectrometry, and thermogravimetric-differential thermogravimetric studies. The results suggest that the mononuclear complexes have a metal to ligand mole ratio of 1:2 and the metal(II) ions are coordinated with the phenolic oxygen and imine nitrogen atoms. Octahedral structures are proposed for the complexes of the Schiff base ligand. Furthermore, the complexes were checked for their efficiency to decolorize the dye methylene blue. In our experiments we found that metal(II) complexes had an acceptable decolorization efficiency against the dye methylene blue.
Keywords
EN
Contributors
author
  • Faculty of Engineering, Celal Bayar University, Manisa, Turkey
author
  • Faculty of Science and Art, Süleyman Demirel University, Isparta, Turkey
author
  • Faculty of Science and Art, Mehmet Akif Ersoy University, Burdur, Turkey
References
  • [1] M. Negoiu, S. Pasculescu, T. Rosu, R. Georgescu, C. Draghici, Rev. Chim. (Bucharest) 61, 762 (2010)
  • [2] A. Nishinaga, T. Yamada, H. Fujisawa, K. Ishizaki, H. Ihara, T. Matsuura, J. Mol. Catal. 48, 249 (1988), doi: 10.1016/0304-5102(88)85009-0
  • [3] Y. Hamada, IEEE Trans. Electron Devices 44, 1208 (1997, doi: 10.1109/16.605456
  • [4] A.I. Hanafy, A.K.T. Maki, M.M. Mostafa, Transition Met. Chem. 32, 960 (2007), doi: 10.1007/s11243-007-0268-5
  • [5] I. Arslan, I.A. Balcioglu, T. Tuhkanen, D. Bahnemann, J. Environ. Eng. 126, 903 (2000), doi: 10.1061/(ASCE)0733-9372(2000)126:10(903)
  • [6] S.K. Chaudhuri, B. Sur, J. Environ. Eng. 126, 583 (2000), doi: 10.1061/(ASCE)0733-9372(2000)126:7(583)
  • [7] N. Levin, W.H. Hartung, J. Org. Chem. 7, 408 (1942), doi: 10.1021/jo01199a002
  • [8] M. Gaber, M.M. Ayad, Y.S.Y. El-Sayed, Spectrochim. Acta, Part A 62, 694 (2005), doi: 10.1016/j.saa.2005.02.039
  • [9] N.M. Shauib, A.A. Elassar, A. El-Dissouky, Spectrochim. Acta, Part A 63, 714 (2006), doi: 10.1016/j.saa.2005.06.024
  • [10] G. Das, R. Shukla, S. Mandal, R. Singh, P.K. Bharadwaj, J. van Hall, K.H. Whitmire, Inorg. Chem. 36, 323 (1997), doi: 10.1021/ic9510371
  • [11] C.A. McAuliffe, R.V. Parish, F.M. Ashmawy, R.M. Issa, S.A. Amer, J. Chem. Soc. Dalton Trans. 1987, 2009 (1987), doi: 10.1039/DT9870002009
  • [12] I.A. Kahwa, J. Selbin, T.C.Y. Hsieh, R.A. Laine, Inorg. Chim. Acta 118, 179 (1986), doi: 10.1016/S0020-1693(00)81385-7
  • [13] M.M.H. Khalil, M.M.Mashaly, Chin. J. Chem. 26, 1669 (2008), doi: 10.1002/cjoc.200890302
  • [14] W.J. Geary, Coord. Chem. Rev. 7, 81 (1971), doi: 10.1016/S0010-8545(00)80009-0
  • [15] F. Magalhaes, F.C.C. Moura, J.D. Ardisson, R.M. Lago, Mater. Res. 11, 307 (2008, doi: 10.1590/S1516-14392008000300013
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv129n213kz
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.