Terrylene in a 2,3-Dichloronaphthalene Crystal. New System for Optical Single-Molecule Investigations

• Authors: M. Białkowska , W. Chaładaj , A. Makarewicz , B. Kozankiewicz
• Languages of publication: EN

Abstracts

EN

Results of optical studies of a new single-molecule system, terrylene molecules in a 2,3-dichloronaphthalene crystal, are presented for the first time. Analysis of the second-order fluorescence intensity correlation function shows that the external heavy-atom effect (due to the chlorine atoms) contributes to the increase of the intersystem crossing rate constant for the S₁ → T₁ transition, by one order of magnitude, whereas the rate constant for the T₁ → S₀ transition is only weakly influenced.

Keywords

EN

33.50.Dq; 82.37.-j

Discipline

• 82.37.-j: Single molecule kinetics
• 33.50.Dq: Fluorescence and phosphorescence spectra

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2015
• Volume: 128
• Issue: 3
• Pages: RK.128.3.1-1-RK.128.3.1-4

Dates

published

2015-9

received

2015-1-016

Contributors

author

M. Białkowska

• Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw, Poland

author

W. Chaładaj

• Institute of Organic Chemistry, Polish Academy of Sciences, M. Kasprzaka 44/52, 01-224 Warsaw, Poland

author

A. Makarewicz

• Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw, Poland

author

B. Kozankiewicz

• Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warsaw, Poland

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Identifiers

DOI

10.12693/APhysPolA.128.RK.128.3.1-1