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Abstracts
The density of electron states of layered crystal intercalated by guests of different nature is calculated within the framework of virtual crystal considering filling of both octahedral and tetrahedral interstitial hollows. It is found that the shift of the gap of density of states is caused firstly by the nature of intercalant (placing of ground energy states of both intercalants) and their average concentrations. In the case when one type of intercalant gives localized level in the forbidden gap and another intercalant forms the resonance one in the conductive band the gap disappears. Relaxation time corresponding to the transitions from one to another band is calculated.
Discipline
Journal
Year
Volume
Issue
Pages
225-227
Physical description
Dates
published
2015-08
Contributors
author
- National University "Lvivska Politechnika", 13, Bandera Str., L'viv, 79013, Ukraine
author
- University of Rzeszów, Centre for Microelectronics and Nanotechnology, S. Pigonia 1, 35-959 Rzeszów, Poland
References
- [1] M. Elhabiri, A.-M. Abrecht-Gary, Coord. Chem. Rev. 252, 1079 (2008), doi: 10.1016/j.ccr.2007.019.014
- [2] B.P. Zakharchenya, Phys.-Usp. 175, 625 (2005), doi: 10.3367/UFNr.0175.200506d.0629
- [3] I.V. Stasyuk, Yu.I. Dublenych, Phys. Rev. B 72, 224209 (2005), doi: 10.1103/PhysRevB.72.224209
- [4] N.K. Tovstyuk, Visnyk Lviv Univ. Ser. Phys. 48, 109 (2013)
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv128n225kz