Optical Transition, Excitation, and Emission Properties of Poly(N-Vinlycarbazole) Blended with Poly(Vinylidene Fluoride-co-Hexafluoropropene) and Polyvinylpyrrolidone

• Authors: A. Alias , Z. Zabidi , M. Harun , M. Yahya , A. Ali
• Languages of publication: EN

Abstracts

EN

We present the results concerning the excitation and emissions spectra of poly(N-carbazole) (PVK) blended with poly(vinylidene fluoride-co-hexafluoropropene), (PVDF-HfP) and polyvinylpyrrolidone (PVP). Thin films of PVK blended with PVDF-HfP (PVK:PVDF-HfP) and PVP (PVK:PVP) were prepared using doctor blade technique on spectrosil substrate. The influences of polymer blends to the excitation and emission spectra were observed under UV excitation source of a xenon lamp. The result shows a discrepancy in the maximum excitation and emission for each samples. The possible energy transfer and recombination mechanisms have been related with singlet-singlet semi-empirical INDO electronic calculation and FTIR measurements.

Keywords

EN

07.60.-j; 31.15.bu; 81.05.Lg; 82.35.Lr

Discipline

• 82.35.Lr: Physical properties of polymers
• 07.60.-j: Optical instruments and equipment(see also 87.64.M- Optical microscopy in biological and medical physics; for optical sources, see 42.72.-g; see also 42.79.-e Optical elements, devices and systems; for optoelectronic devices, see 85.60.-q; for optical telescopes, see 95.55.Cs; for photometric, polarimetric, and spectroscopic equipment in astronomy, see 95.55.Qf)
• 81.05.Lg: Polymers and plastics; rubber; synthetic and natural fibers; organometallic and organic materials(for polymers and organic materials in electrochemistry, see 82.45.Wx)
• 31.15.bu: Semi-empirical and empirical calculations (differential overlap, Hückel, PPP methods, etc.)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2015
• Volume: 127
• Issue: 4
• Pages: 1075-1078

Dates

published

2015-04

Contributors

author

A. Alias

• Faculty of Applied Science, Universiti Teknologi Mara (Perak) Kampus Tapah 35400 Tapah Road, Perak, Malaysia
• Ionic Materials & Devices (iMADE) Research Laboratory, Institute of Sciences, Universiti Teknologi MARA 40450 Shah Alam, Selangor D.E., Malaysia

author

Z. Zabidi

• Faculty of Applied Science, Universiti Teknologi Mara (Perak) Kampus Tapah 35400 Tapah Road, Perak, Malaysia

author

M. Harun

• Ionic Materials & Devices (iMADE) Research Laboratory, Institute of Sciences, Universiti Teknologi MARA 40450 Shah Alam, Selangor D.E., Malaysia

author

M. Yahya

• Faculty of Defence Science & Technology, Universiti Pertahanan Nasional Malaysia, Kem Sg. Besi, 57000 Kuala Lumpur, Malaysia

author

A. Ali

• Ionic Materials & Devices (iMADE) Research Laboratory, Institute of Sciences, Universiti Teknologi MARA 40450 Shah Alam, Selangor D.E., Malaysia

References

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Identifiers

DOI

10.12693/APhysPolA.127.1075