The Effect of Inorganic Nano Powder Additives in TEGDME for Lithium Air Batteries

• Authors: M. Kartal , M. Uysal , T. Cetinkaya , A. Alp , H. Akbulut
• Languages of publication: EN

Abstracts

EN

SiO₂ and Al₂O₃ nano fillers were added to an electrolyte composed of a solution 1 M LiPF₆ in tetra ethylene glycol dimethyl ether (TEGDME) and the effects of these nano powders on capacity and cycling performances were investigated. Galvanostatic charge/discharge (GC) measurements were performed in the assembled Li-air cells by using the nanocomposite electrolytes. The discharge capacities of these cells were cyclically tested by a battery tester at a constant current in the voltage range between 2.15 V and 4.25 V. Discharge products of nanocomposite electrolytes were characterized by SEM and XRD spectroscopies. The electrochemical results demonstrated that Al₂O₃ reinforced electrolyte showed higher discharge capacity and cyclability than those of SiO₂ reinforced electrolyte.

Keywords

EN

88.80.F-; 88.80.ff; 82.45.Gj; 82.45.Wx; 81.07.-b

Discipline

• 81.07.-b: Nanoscale materials and structures: fabrication and characterization(for structure of nanoscale materials, see 61.46.-w; for nanostructured materials in electrochemistry, see 82.45.Yz; see also 62.23.-c Structural classes of nanoscale systems in mechanical properties of condensed matter)
• 82.45.Gj: Electrolytes(for polyelectrolytes, see 82.35.Rs and 82.45.Wx; see also 66.30.H- Self-diffusion and ionic conduction in nonmetals)
• 88.80.ff: Batteries(for lithium-ion batteries, see 82.47.Aa; for lead-acid, nickel-metal hydride batteries, see 82.47.Cb; see also 88.85.jk, and 88.85.jm in advanced vehicles)
• 88.80.F-: Energy storage technologies(see also 84.60.Ve Energy storage systems, including capacitor banks)
• 82.45.Wx: Polymers and organic materials in electrochemistry(see also 82.35.-x Polymers: properties; reactions; polymerization)

• Journal: Acta Physica Polonica A
• Year: 2015
• Volume: 127
• Issue: 4
• Pages: 1016-1018

Dates

published

2015-04

Contributors

author

M. Kartal

• Sakarya University Engineering Faculty, Department of Metallurgical & Materials Engineering, Esentepe Campus, 54187, Sakarya, Turkey

author

M. Uysal

• Sakarya University Engineering Faculty, Department of Metallurgical & Materials Engineering, Esentepe Campus, 54187, Sakarya, Turkey

author

T. Cetinkaya

• Sakarya University Engineering Faculty, Department of Metallurgical & Materials Engineering, Esentepe Campus, 54187, Sakarya, Turkey

author

A. Alp

• Sakarya University Engineering Faculty, Department of Metallurgical & Materials Engineering, Esentepe Campus, 54187, Sakarya, Turkey

author

H. Akbulut

• Sakarya University Engineering Faculty, Department of Metallurgical & Materials Engineering, Esentepe Campus, 54187, Sakarya, Turkey

References

• [1] L.J. Hardwick, P.G. Bruce, Curr. Opin. Solid State M. 16, 178 (2012), doi: 10.1016/j.cossms.2012.04.001
• [2] W. Xu, J. Hu, M.H. Engelhard, S.A. Towne, J.S. Hardy, J. Xiao, J. Feng, M.Y. Hu, J. Zhang, F. Ding, M.E. Gross, J.G. Zhang, J. Power Sources 215, 240 (2012), doi: 10.1016/j.jpowsour.2012.05.021
• [3] F. Mizuno, K. Takechi, S. Higashi, T. Shiga, T. Shiotsuki, N. Takazawa, Y. Sakurabayashi, S. Okazaki, I. Nitta, T. Kodama, H. Nakamoto, H. Nishikoori, S. Nakanishi, Y. Kotani, H. Iba, J. Power Sources 228, 47 (2013), doi: 10.1016/j.jpowsour.2012.11.077
• [4] C.O. Laoire, S. Mukerjee, K.M. Abraham, E.J. Plichta, M.A. Hendrickson, J. Phys. Chem. C 113, 20127 (2009), doi: 10.1021/jp908090s
• [5] B.D. McCloskey, R. Scheffler, A. Speidel, G. Girishkumar, A.C. Luntz, J. Phys. Chem. C 116, 23897 (2012), doi: 10.1021/jp306680f
• [6] E. Nasybulin, W. Xu, M.H. Engelhard, Z. Nie, X.S. Li, J.G. Zhang, J. Power Sources 243, 899 (2013), doi: 10.1016/j.jpowsour.2013.06.097
• [7] C.Ó. Laoire, S. Mukerjee, E.J. Plichta, M.A. Hendrickson, K.M. Abraham, J. Electrochem. Soc. 158, A302 (2011), doi: 10.1149/1.3531981
• [8] H. Tokuda, M. Watanabe, Electrochim. Acta 48, 2085 (2003), doi: 10.1016/S0013-4686(03)00189-0
• [9] D. Sharma, A. Mukherjee, International Journal of Emerging Technology and Advanced Engineering 4, 60 (2014)
• [10] B.D. McCloskey, A. Speidel, R. Scheffler, D.C. Miller, V. Viswanathan, J.S. Hummelshøj, J.K. Nørskov, A.C. Luntz, J. Phys. Chem. Lett. 3, 997 (2012), doi: 10.1021/jz300243r
• [11] M. Balaish, A. Kraytsberg, Y. Ein-Eli, Phys. Chem. Chem. Phys. 16, 2801 (2013), doi: 10.1039/C3CP54165G

Identifiers

DOI

10.12693/APhysPolA.127.1016