FTIR Study of Nanostructure Perovskite BaTiO_3 Doped with Both Fe^{3+} and Ni^{2+} Ions Prepared by Sol-Gel Technique

• Authors: A. Abdel Aal , T. Hammad , M. Zawrah , I. Battisha , A. Abou Hammad
• Languages of publication: EN

Abstracts

EN

Pure barium titanate BaTiO_3 (BT) and BT doped with two different transition elements Fe^{3+} and Ni^{2+} at 5 mol.% (BT5Fe and BT5Ni, respectively) as constant concentration in powder form have been prepared by sol-gel method using barium acetate, titanium(IV) n-butoxide, iron and nickel nitrates as precursor materials. The microstructure of BT and the influence of Fe and Ni dopants on it were investigated by X-ray diffraction and Fourier transform infrared spectroscopy. X-ray diffraction shows that tetragonal phase is dominant for pure BT sintered for 4 h at 800°C. Scanning electron microscopy and transmission electron microscopy were used to study surface morphology and particle size distribution for BT5Fe and BT5Ni, respectively. The presence of hydroxyl defects were verified by Fourier transform infrared spectroscopy for (BaTi_{1-x}Fe_{x}O_{3-x/2}) (BT_xFe), where x=0.005, 0.01, 0.05, and 0.07 and (BaTi_{1-x}Ni_{x}O_{3-x/2}) (BT_xNi), where x=0.005, 0.01, 0.03, 0.05, and 0.07.

Keywords

EN

81.20.Fw; 81.07.Bc; 64.70.kg; 61.05.C-; 78.30.Ly; 81.10.Aj

Discipline

• 78.30.Ly: Disordered solids
• 81.07.Bc: Nanocrystalline materials
• 81.20.Fw: Sol-gel processing, precipitation(for reactions in sol-gels, see 82.33.Ln; for sol-gels as disperse system, see 82.70.Gg)
• 61.05.C-: X-ray diffraction and scattering(for x-ray diffractometers, see 07.85.Jy; for x-ray studies of crystal defects, see 61.72.Dd, Ff)
• 64.70.kg: Semiconductors
• 81.10.Aj: Theory and models of crystal growth; physics and chemistry of crystal growth, crystal morphology, and orientation(see also 61.50.Nw Crystal stoichiometry)

• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 126
• Issue: 6
• Pages: 1318-1321

Dates

published

2014-12

received

2012-11-10

(unknown)

2014-03-16

Contributors

author

A. Abdel Aal

• Helwan University, Physics Department, Helwan, Cairo, Egypt

author

T. Hammad

• Helwan University, Physics Department, Helwan, Cairo, Egypt

author

M. Zawrah

• National Research Center (NRC), Ceramic Department, Doky, Giza, Egypt

author

I. Battisha

• National Research Center (NRC), Solid State Physics Department, Doky, Giza, Egypt

author

A. Abou Hammad

• National Research Center (NRC), Solid State Physics Department, Doky, Giza, Egypt

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Identifiers

DOI

10.12693/APhysPolA.126.1318