Title variants
Languages of publication
Abstracts
The local structure, two optical band positions and three electronic spin resonance parameters for Cu^{2+} centers at the tetragonally-distorted octahedral sites in ZnO-Bi_2O_3-B_2O_3-CuO glasses are calculated from the high-order perturbation method based on the two-spin-orbit-parameter model, where the contributions from both the spin-orbit coupling parameters of central d^{n} ion and ligand ion are included. The theoretical results are in good agreement with the experimental values. The calculations show that the high-order perturbation method based on the two-spin-orbit-parameter model is effective in the explanations of optical spectra, electronic spin resonance parameters and local distortion structure for d^{9} ions in glasses.
Discipline
- 61.72.Bb: Theories and models of crystal defects
- 76.30.Fc: Iron group (3d) ions and impurities (Ti-Cu)
- 75.10.Dg: Crystal-field theory and spin Hamiltonians(see also 71.70.Ch Crystal and ligand fields)
- 76.30.-v: Electron paramagnetic resonance and relaxation(see also 33.35.+r Electron resonance and relaxation in atomic and molecular physics; 87.80.Lg Magnetic and paramagnetic resonance in biological physics)
Journal
Year
Volume
Issue
Pages
1293-1295
Physical description
Dates
published
2014-12
received
2014-05-23
(unknown)
2014-12-05
Contributors
author
- Physical Experiment Center, School of Optoelectronic Information, Chongqing University of Technology, Chongqing 400054, China
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv126n613kz