Deformation-Induced Structural Transformations in Molecular Crystals

• Authors: D. Rybin , G. Konygin , V. Porsev , E. Yelsukov , I. Arsentyeva , V. Boldyrev
• Languages of publication: EN

Abstracts

EN

The physical mechanisms of the deformation-induced structural transformations in molecular crystals, including morphological changes, amorphization and molecular polymorphous conversions in nano-dispersed bioinorganic compounds are discussed in this work. Integrated study using direct structural and structure-sensitive spectroscopic methods allowed obtaining the data on polymorphous transformations, taking place during mechanical activation in calcium gluconate monohydrate (CG). One of the possible reasons for lattice polymorphous transformations and amorphization, observed in the course of mechanical activation of low-symmetry molecular crystals, might be the spatial molecular isomerization. In this case, the disappearance of the translational invariance of the lattice is conditioned by the simultaneous coexistence of the reactants and reaction products, which have different stereo-organization of the molecular structure.

Keywords

EN

82.33.Pt; 81.20.-n; 61.50.Ks

Discipline

• 81.20.-n: Methods of materials synthesis and materials processing(see also 61.72.U- Doping and impurity implantation; for crystal growth, see 81.10.-h; for film growth, deposition and epitaxy, see 81.15.-z)
• 82.33.Pt: Solid state chemistry
• 61.50.Ks: Crystallographic aspects of phase transformations; pressure effects(see also 81.30.Hd in materials science)

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 126
• Issue: 4
• Pages: 1014-1018

Dates

published

2014-10

Contributors

author

D. Rybin

• Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia

author

G. Konygin

• Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia

author

V. Porsev

• Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia

author

E. Yelsukov

• Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia

author

I. Arsentyeva

• Moscow State Open University, 107996 Moscow, Russia

author

V. Boldyrev

• Institute of Solid State Chemistry and Mechanochemistry, 630128 Novosibirsk, Russia
• Novosibirsk State University, 630090 Novosibirsk, Russia

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Identifiers

DOI

10.12693/APhysPolA.126.1014