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2014 | 126 | 4 | 1014-1018
Article title

Deformation-Induced Structural Transformations in Molecular Crystals

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Abstracts
EN
The physical mechanisms of the deformation-induced structural transformations in molecular crystals, including morphological changes, amorphization and molecular polymorphous conversions in nano-dispersed bioinorganic compounds are discussed in this work. Integrated study using direct structural and structure-sensitive spectroscopic methods allowed obtaining the data on polymorphous transformations, taking place during mechanical activation in calcium gluconate monohydrate (CG). One of the possible reasons for lattice polymorphous transformations and amorphization, observed in the course of mechanical activation of low-symmetry molecular crystals, might be the spatial molecular isomerization. In this case, the disappearance of the translational invariance of the lattice is conditioned by the simultaneous coexistence of the reactants and reaction products, which have different stereo-organization of the molecular structure.
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Contributors
author
  • Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia
author
  • Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia
author
  • Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia
author
  • Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, 426000 Izhevsk, Russia
author
  • Moscow State Open University, 107996 Moscow, Russia
author
  • Institute of Solid State Chemistry and Mechanochemistry, 630128 Novosibirsk, Russia
  • Novosibirsk State University, 630090 Novosibirsk, Russia
References
  • [1] B. Gyurcsik, L. Nagy, Coord. Chem. Rev. 203, 81 (2000), doi: 10.1016/S0010-8545(99)00183-6
  • [2] C.G. Hartinger, A.A. Nazarov, S.M. Ashraf, P.J. Dyson, B.K. Keppler, Cur. Med. Chem. 15, 2574 (2008), doi: 10.2174/092986708785908978
  • [3] T.P. Shakhtshneider, V.V. Boldyrev, in: Reactivity of molecular solids, The Molecular Solid State, Vol. 3, Eds. E. Boldyreva, V. Boldyrev, Wiley, 1999, p. 271 http://eu.wiley.com/WileyCDA/WileyTitle/productCd-0471999075.html
  • [4] P.A.M. Williams, D.A. Barrio, S.B. Etcheverry, E.J. Baran, J. Inorg. Biochem. 98, 333 (2004), doi: 10.1016/j.jinorgbio.2003.10.019
  • [5] V.V. Boldyrev, Bull. Siber. Branch RAMS 96, 143 (2000)
  • [6] N. Chieng, Z. Zujovic, G. Bowmaker, T. Rades, D. Saville, Int. J. Pharmaceut. 327, 36 (2006), doi: 10.1016/j.ijpharm.2006.07.032
  • [7] E.P. Yelsukov, G.A. Dorofeev, A.V. Zagainov, N.F. Vildanova, A.N. Maratkanova, Mater. Sci. Eng. 369, 16 (2004), doi: 10.1016/j.msea.2003.08.054
  • [8] R. Zallen, J. Non-Cryst. Solids 75, 3 (1985), doi: 10.1016/0022-3093(85)90196-6
  • [9] G.N. Konygin, F.Z. Gilmutdinov, S.G. Bystrov, O.V. Karban, G.A. Dorofeev, E.P. Yelsukov, A.A. Shakov, N.S. Strelkov, E.P. Tul'kin, V.V. Pozdeev, S.B. Shishkin, P.N. Maksimov, A.N. Filippov, V.V. Korepanova, Chem. Sustain. Develop. 13, 249 (2005)
  • [10] N.S. Strelkov, G.N. Konygin, D.S. Rybin, V.V. Pozdeev, N.A. Kir'yanov, O.V. Yakovenko, P.N. Maksimov, E.P. Yelsukov, Yu.Ya. Efremov, D.R. Sharafutdinova, V.Yu. Petukhov, G.G. Gumarov, Almanac Clin. Med. (Almanakh klinicheskoi mediciny) 17, 366 (2008) (in Russian)
  • [11] D.S. Rybin, G.N. Konygin, V.E. Porsev, E.P. Yelsukov, M.A. Eremina, D.R. Sharafutdinova, Yu.Ya. Efremov, G.G. Gumarov, V.Yu. Petukhov, O.I. Gnezdilov, M.M. Akhmetov, K.M. Salikhov, V.V. Boldyrev, Chem. Phys. Mesosc. 15, 429 (2013) (in Russian)
  • [12] D.R. Sharafutdinova, Yu.Ya. Efremov, I.H. Rizvanov, G.N. Konygin, D.S. Rybin, N.S. Strelkov, J. Struct. Chem. 51, S142 (2010), doi: 10.1007/s10947-010-0203-z
  • [13] M.W. Wieczorek, J. Blaszczyk, B.W. Król, Acta Crystallogr. C52, 1193 (1996), doi: 10.1107/S0108270195011930
  • [14] F.J.W.J. Labuschagne, W.W. Focke, J. Mater. Sci. 38, 1249 (2003), doi: 10.1023/A:1022818022650
  • [15] A. Valor, E. Reguera, E. Torres-García, S. Mendoza, F. Sanchez-Sinencio, Thermochim. Acta 389, 133 (2002), doi: 10.1016/S0040-6031(02)00010-2
  • [16] I.G. Konkina, S.P. Ivanov, O.A. Knyazeva, V.A. Davydova, E.V. Vasil'eva, L.M. Karachurina, F.A. Zarudii, I.A. Ionova, R.K. Gaifutdinova, Yu.I.`Murinov, Pharmaceut. Chem. J. 36, 18 (2002), doi: 10.1007/s10947-010-0203-z
  • [17] A.V. Iogansen, in: Hydrogen Bonding, Ed. N.D. Sokolov, Nauka, Moscow 1981, p. 112 (in Russian)
  • [18] M.L. Hackert, R.A. Jacobson, Acta Crystallogr. B27, 203 (1971), doi: 10.1107/S0567740871001900
  • [19] H.A. Tajmir-Riahi, Can. J. Chem. 67, 651 (1989), doi: 10.1139/v89-098
  • [20] H.A. Tajmir-Riahi, J. Inorg. Biochem. 39, 33 (1990), doi: 10.1016/0162-0134(90)80013-N
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv126n435kz
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