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2014 | 125 | 5 | 1075-1083
Article title

A Method of Solving the Eigenproblem of the Atomic Ion Hamiltonians. I. Theory

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EN
Abstracts
EN
The aim of this paper is to present a procedure for determining the power series in N-1/Z for the approximate energy levels and eigenspaces of the nonrelativistic Hamiltonians H^{(N,Z)} with N-electrons and nuclear charge Z. To this effect the theory of the best multiconfigurational approximations is applied.
Keywords
Year
Volume
125
Issue
5
Pages
1075-1083
Physical description
Dates
published
2014-05
received
2012-09-30
(unknown)
2014-03-26
References
  • [1] S. Pruski, 'Generalized one-particle analysis of systems of n$ fermions', Lecture given at 5th Symp. on Mathematical Physics, Toruń, December 1973
  • [2] S. Pruski, Physica 37, 246 (1967)
  • [3] T. Kato, Perturbation Theory for Linear Operators, Springer, Berlin 1966
  • [4] D.R. Hartree, Proc. Camb. Philos. Soc. 24, 89 (1928)
  • [5] V.A. Fock, Z. Phys. 61, 126 (1930)
  • [6] A. Akhieser, I.M. Glazman, Theory of linear operators in Hilbert space, Frederick Ungar Publishing Company, New York 1961
  • [7] D.J. Klein, J. Chem. Phys. 61, 786 (1974)
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv125n502kz
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