Olefin Hydrogenation with Single-Site Gold

• Authors: J. Szlachetko , C. Lothschütz , J. Sá
• Languages of publication: EN

Abstracts

EN

Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent group of the coordinating group at position 5. Resonant inelastic X-ray scattering experiments and theoretical calculations revealed an increase in unoccupied 5d states of Au when the substituent group is a donating group, which leads to a dramatic increase in catalytic activity.

Keywords

EN

82.80.Dx; 82.20.-w; 82.80.Ej

Discipline

• 82.80.Dx: Analytical methods involving electronic spectroscopy
• 82.80.Ej: X-ray, Mössbauer, and other γ-ray spectroscopic analysis methods
• 82.20.-w: Chemical kinetics and dynamics

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 125
• Issue: 4
• Pages: 940-943

Dates

published

2014-04

Contributors

author

J. Szlachetko

• Paul Scherrer Institute (PSI), 5232 Villigen-PSI, Switzerland
• Institute of Physics, Jan Kochanowski University, 25-406 Kielce, Poland

author

C. Lothschütz

• Syngenta Crop Protection, Münchwilen AG, Breitenloh-5, CH-4333 Muenchwilen, Switzerland

author

J. Sá

• Laboratoire de Spectroscopie Ultrarapide, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland

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Identifiers

DOI

10.12693/APhysPolA.125.940