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2014 | 125 | 4 | 940-943
Article title

Olefin Hydrogenation with Single-Site Gold

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Abstracts
EN
Butene hydrogenation activity is intimately connected with the occupied and unoccupied electronic states of gold active site. We prepare well-defined Au(III) sites in IRMOF-3 structure, and tuned the metal density-of-states by replacing the substituent group of the coordinating group at position 5. Resonant inelastic X-ray scattering experiments and theoretical calculations revealed an increase in unoccupied 5d states of Au when the substituent group is a donating group, which leads to a dramatic increase in catalytic activity.
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Contributors
author
  • Paul Scherrer Institute (PSI), 5232 Villigen-PSI, Switzerland
  • Institute of Physics, Jan Kochanowski University, 25-406 Kielce, Poland
  • Syngenta Crop Protection, Münchwilen AG, Breitenloh-5, CH-4333 Muenchwilen, Switzerland
author
  • Laboratoire de Spectroscopie Ultrarapide, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv125n420kz
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