Investigation of Infrared and Raman Spectra of TeO_2-Nb_2O_5-TiO_2 Glasses

• Authors: İ. Kabalci , H. Gökçe
• Languages of publication: EN

Abstracts

EN

X-ray diffraction, infrared (IR), Raman spectroscopy and scanning electron microscope techniques have been used to investigate the microstructural properties of the glass materials. In this work, a new type of tellurite based optical glasses with TeO_2/Nb_2O_5/TiO_2 for different xNb_2O_5 (x = 5, 10, 15, and 20 mol.%) glass compositions at constant 5 mol.% TiO_2 ratio were prepared. The effect of Nb_2O_5 contents on the structural unit of (95-x)TeO_2-(x)Nb_2O_5-5TiO_2 glass network, and the intensity ratios of the Raman peaks were investigated. The results indicate that for different Nb_2O_5 content 5 to 20 mol.% in the glass system, three vibrational peaks around 650, 800, and 920 cm^{-1} which correspond to the structural bonding of the glass were observed in the range of 500-2000 cm^{-1} for the IR spectra. Furthermore, from the Raman results a structural evolution was determined with the number of structural units such as [NbO_6]^{7-}, TeO_{3+1} (polyhedra), TeO_4 (trigonal bipyramids), TeO_3 (trigonal pyramids) or TeO_{3+1} (polyhedra), and [NbO_4]^{3-} for this ternary glass system.

Keywords

EN

42.70.Ce; 61.05.Cp; 82.80.Gk; 78.30.Ly

Discipline

• 42.70.Ce: Glasses, quartz
• 78.30.Ly: Disordered solids
• 82.80.Gk: Analytical methods involving vibrational spectroscopy

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 125
• Issue: 4
• Pages: 877-881

Dates

published

2014-04

Contributors

author

İ. Kabalci

• Department of Physics, Education Faculty, Harran University, Sanliurfa, Turkey

author

H. Gökçe

• Department of Metallurgical and Materials Engineering, İstanbul Technical University Maslak, 34469 İstanbul, Turkey

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Identifiers

DOI

10.12693/APhysPolA.125.877