The Influence of Reduction Process on the Iron-Molybdenum Nanoparticles in Modified MCM-41 Silica

• Authors: Z. Surowiec , M. Wiertel , W. Gac , M. Budzyński
• Languages of publication: EN

Abstracts

EN

Iron-molybdenum silica mesoporous materials were obtained by the application of direct hydrothermal method. The influence of high temperature samples reduction in the H_2 flow on their structural and magnetic properties was studied. Four samples with different metal contents relative to silica were investigated. The study was carried out by means of X-ray diffraction, ^{57}Fe Mössbauer spectroscopy and the temperature programmed reduction method. With an increasing metals content, primary pores of MCM-41 transformed into the bottle-like pores, and then into the slit-like ones. Reduction and heat treatment caused the α-Fe, Fe_2Mo, and Fe-Mo alloy formation. Iron and molybdenum atoms after being released into the silica matrix, where they were embedded, create clusters or crystallites. It was observed that the high temperature reduction caused partial transformation of highly dispersed Fe-Mo oxides species initially embedded in silica walls into crystallites big enough to give magnetic sextet component in the Mössbauer spectra.

Keywords

EN

76.80.+y; 78.67.Bf; 78.67.Rb; 75.20.-g

Discipline

• 78.67.Bf: Nanocrystals, nanoparticles, and nanoclusters
• 75.20.-g: Diamagnetism, paramagnetism, and superparamagnetism
• 76.80.+y: Mössbauer effect; other γ-ray spectroscopy(see also 33.45.+x Mössbauer spectra—in atomic and molecular physics; for biophysical applications, see 87.64.kx; for chemical analysis applications, see 82.80.Ej)
• 78.67.Rb: Nanoporous materials

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 125
• Issue: 3
• Pages: 846-849

Dates

published

2014-03

Contributors

author

Z. Surowiec

• Institute of Physics, M. Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 1, 20-031 Lublin, Poland

author

M. Wiertel

• Institute of Physics, M. Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 1, 20-031 Lublin, Poland

author

W. Gac

• Faculty of Chemistry, M. Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 1, 20-031 Lublin, Poland

author

M. Budzyński

• Institute of Physics, M. Curie-Skłodowska University, pl. M. Curie-Skłodowskiej 1, 20-031 Lublin, Poland

References

• [1] A. Błachowski, K. Ruebenbauer, J. Żukrowski, J. Przewoźnik, J. Alloys Comp. 482, 23 (2009), doi:10.1016/j.jallcom.2009.03.177
• [2] J.J. Uhlrich, J. Sainio, Y. Lei, D. Edwards, R. Davies, M. Bowker, S. Shaikhutdinov, H.-J. Freund, Surf. Sci. 605, 1550 (2011), doi:10.1016/j.susc.2011.05.028
• [3] T.H. Kim, B. Ramachandra, J.S. Choi, M.B. Saidutta, K.Y. Choo, S.D. Song, Y.W. Rhee, Catal. Lett. 98, 161 (2004), doi:10.1007/s10562-004-7932-6
• [4] M. Wiertel, Z. Surowiec, M. Budzyński, W. Gac, Nukleonika 58, 245 (2013)
• [5] Z. Surowiec, M. Wiertel, A. Marynowska, W. Gac, W. Zawadzki, Nukleonika 58, 137 (2013)
• [6] H. Zhang, Z. Li, X. Fu, J.P. Huang, Y. Zhang, J. Mol. Catal. 3, 139 (1998)
• [7] R. Morales, D.U. Sichen, S. Seetharaman, Metall. Mater. Trans. B 34, 661 (2003), doi:10.1007/s11663-003-0037-6
• [8] H. Zhang, J. Shen, X. Ge, J. Solid State Chem. 117, 127 (1999)
• [9] H.L. Marcus, M.E. Fine, L.H. Schwartz, J. Appl. Phys. 38, 4750 (1967), doi:10.1063/1.1709214

Identifiers

DOI

10.12693/APhysPolA.125.846