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2014 | 125 | 2 | 669-672
Article title

Structural Analysis of Ce Doped La_{1-x}Sr_xCo_{1-y}Fe_yO_{3-δ} Nanopowders Synthesized by Glycine-Nitrate Gel Combustion

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EN
Abstracts
EN
Ce doped La_{1-x}Sr_xCo_{1-y}Fe_yO_3 (LCSCF) is a widely used cathode material due to its high catalytic activity for oxygen reduction and high oxygen exchange coefficient. LCSCF is also known with its high ionic and electronic conductivities and low electrode polarization losses which are highly critical properties for low temperature solid oxide fuel cell applications. In this study, structural properties of the LCSCF cathode nanopowder materials synthesized by glycine-nitrate gel combustion have been investigated by X-ray diffraction, differential scanning calorimetry, scanning electron microscopy, and nanosizer. Synthesized nanopowders represent volcanic ash like structures and morphologies. Ce, Sr, Co, and Fe are found to have significant effects on the structural properties of powders in terms of powders morphology, agglomerate structure, crystallite size and also lattice parameter of perovskite crystal. All synthesized ash powders have particle sizes around 50-600 nm, varying crystalline structures of perovskite and fluorite depending on molar ratio of Ce in the composition. Increasing molar Ce ratio over 0.4 is found to lead to the formation of a separate nano ceria phase in fluorite crystal structure on the surface of the synthesized powder.
Keywords
Contributors
author
  • Kocaeli University, Faculty of Engineering, Department of Metallurgical and Materials Engineering TR-41380 Kocaeli, Turkey
author
  • Gebze Institute of Technology, Faculty of Engineering, Department of Materials Science and Engineering TR-41400 Gebze/Kocaeli, Turkey
author
  • Gebze Institute of Technology, Faculty of Engineering, Department of Materials Science and Engineering TR-41400 Gebze/Kocaeli, Turkey
  • Gebze Institute of Technology, Faculty of Engineering, Department of Materials Science and Engineering TR-41400 Gebze/Kocaeli, Turkey
author
  • Gebze Institute of Technology, Faculty of Engineering, Department of Materials Science and Engineering TR-41400 Gebze/Kocaeli, Turkey
author
  • Gebze Institute of Technology, Faculty of Engineering, Department of Materials Science and Engineering TR-41400 Gebze/Kocaeli, Turkey
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv125n2162kz
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