Cyclic Performance Study of Silicon/Carbon Nanotube Composite Anodes Using Electrochemical Impedance Spectroscopy

• Authors: U. Tocoglu , O. Cevher , T. Cetinkaya , M. Guler , H. Akbulut
• Languages of publication: EN

Abstracts

EN

Silicon based carbon nanotube composites were produced and their galvanostatic cycling properties analyzed depended on the electrochemical impedance spectroscopy. Composite anodes were produced via vacuum filtration and DC magnetron sputtering technique. Carbon nanotube papers were produced with vacuum filtration as substrate for silicon deposition and silicon was sputtered onto carbon nanotube papers via DC magnetron sputtering. Scanning electron microscopy and X-ray diffraction analysis were conducted for structural analysis of anodes. CR2016 coin cells were assembled for electrochemical tests. Electrochemical performance of anodes was tested via galvanostatic charge/discharge (100 cycles) analysis. Electrochemical impedance spectroscopy was carried out at every 25 charge/discharge cycle to determine relation between cyclic performance and electrochemical impedance of cells.

Keywords

EN

82.47.Aa

Discipline

• 82.47.Aa: Lithium-ion batteries

• Journal: Acta Physica Polonica A
• Year: 2014
• Volume: 125
• Issue: 2
• Pages: 290-292

Dates

published

2014-02

Contributors

author

U. Tocoglu

• Sakarya University, Engineering Faculty, Department of Metallurgical and Materials Engineering, Esentepe Campus 54187, Turkey

author

O. Cevher

• Sakarya University, Engineering Faculty, Department of Metallurgical and Materials Engineering, Esentepe Campus 54187, Turkey

author

T. Cetinkaya

• Sakarya University, Engineering Faculty, Department of Metallurgical and Materials Engineering, Esentepe Campus 54187, Turkey

author

M. Guler

• Sakarya University, Engineering Faculty, Department of Metallurgical and Materials Engineering, Esentepe Campus 54187, Turkey

author

H. Akbulut

• Sakarya University, Engineering Faculty, Department of Metallurgical and Materials Engineering, Esentepe Campus 54187, Turkey

References

• 1. C. Kang, I. Lahiri, R. Baskaran, W.G. Kim, Y.K. Sun, W. Choi, doi: 10.1016/j.jpowsour.2012.07.050, J. Power Sources 219, 364 (2012)
• 2. H. Wu, Y. Cui, doi: 10.1016/j.nantod.2012.08.004, Nano Today 7, 414 (2012)
• 3. S.H. Nguyen, J.C. Lim, J.K. Lee, doi: 10.1016/j.electacta.2012.03.176, Electrochim. Acta 74, 53 (2012)
• 4. Z. Du, S. Zhang, T. Jiang, R. Lin, J. Zhao, doi: 10.1016/j.electacta.2012.04.052, Electrochim. Acta 74, 222 (2012)
• 5. R. Epur, M.K. Datta, P.N. Kumta, doi: 10.1016/j.electacta.2012.08.054, Electrochim. Acta 85, 680 (2012)
• 6. V. Baranchugov, E. Markevich, E. Pollak, G. Salitra, D. Aurbach, doi: 10.1016/j.elecom.2006.11.014, Electrochem. Commun. 9, 796 (2007)
• 7. M. Thakura, M. Isaacson, S.L. Sinsabaugh, M.S. Wonga, S.L. Biswala, doi: 10.1016/j.jpowsour.2012.01.058, J. Power Sources 205, 426 (2012)
• 8. M.S. Park, G.X. Wang, H.K. Liu, S.X. Doua, doi: 10.1016/j.electacta.2006.01.045, Electrochim. Acta 51, 5246 (2006)

Identifiers

DOI

10.12693/APhysPolA.125.290