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Cu_3RE_2W_4O_{18} tungstates (RE = Gd, Dy-Er) are paramagnets in the temperature range 4.2-300 K visible also in the absence of the energy losses in the curve of the imaginary part of magnetic susceptibility, χ". The negative values of the paramagnetic Curie-Weiss temperature, θ, may suggest the weak antiferromagnetic coupling below 4.2 K. The temperature independent component of magnetic susceptibility has a positive value indicating a domination of the Van Vleck contribution. Calculations of the effective number of the Bohr magnetons revealed that the orbital contribution to the magnetic moment comes mainly from the RE^{3+} ions.
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885-887
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published
2013-11
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author
- University of Silesia, Institute of Physics, Uniwersytecka 4, 40-007 Katowice, Poland
author
- West Pomeranian University of Technology, Department of Inorganic and Analytical Chemistry, al. Piastów 42, 71-065 Szczecin, Poland
author
- University of Silesia, Institute of Physics, Uniwersytecka 4, 40-007 Katowice, Poland
author
- International Laboratory of High Magnetic Fields and Low Temperatures, Gajowicka 95, 53-529 Wrocław, Poland
References
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Publication order reference
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bwmeta1.element.bwnjournal-article-appv124n538kz