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2013 | 124 | 2 | 329-335
Article title

Low Temperature Crystal Structure Behaviour of Complex Yttrium Aluminium Oxides YAlO_3 and Y_3Al_5O_{12}

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Abstracts
EN
Crystal structures of two yttrium aluminium oxides, namely YAlO_3 and Y_3Al_5O_{12}, were investigated in the temperature range 3.4-300 K by high-resolution neutron powder diffraction. Neither traces of phase transformations nor discontinuous changes of physical properties were observed. Thermal expansion of yttrium aluminium oxides was evaluated in terms of 1st order Grüneisen approximation, where the Debye temperatures and the Grüneisen parameters have been estimated for both compositions. Anomalies in the thermal expansion of yttrium aluminium perovskite have been observed and modelled using the Einstein oscillator with negative Grüneisen parameter. Extended bond length analysis revealed significant thermally-driven modifications of the aluminium-oxygen framework.
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author
  • Forschungs-Neutronenequelle Heinz Maier-Leibnitz FRM-II, Technische Universität München, Lichtenbergstrasse 1, D-85748 Garching b. München, Germany
author
  • Lviv Polytechnic National University, 12 Bandera Str, 79013 Lviv, Ukraine
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Document Type
Publication order reference
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv124n222kz
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