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2013 | 123 | 2 | 368-370
Article title

Improvement of Cycling Stability of LiMn_2O_4 Cathode by Al_2O_3 Surface Coating for Li-Ion Batteries

Content
Title variants
Languages of publication
EN
Abstracts
EN
The effect of the Al_2O_3 coating on the charge-discharge cycling performance of spinel powder (LiMn_2O_4) was investigated in the range of 3.5-4.5 V at 1C. The Al_2O_3 coating on the surface of the spinel powder was carried out using the solution method, followed by 500C for 6 h in air. Powder X-ray diffraction pattern of the Al_2O_3-coated spinel LiMn_2O_4 showed that the Al_2O_3 coating medium was not incorporated in the spinel bulk structure. Scanning electron microscopy results showed that the Al_2O_3 coating particles were homogeneously distributed on the surface of LiMn_2O_4 powder particles. The Al_2O_3-coated LiMn_2O_4 retained 92.3% of its original capacity after 30 cycles, showing much better cycle ability than the bare lithium manganese oxide. The improvement of electrochemical performance is attributed to suppression of Mn^{2+} dissolution into electrolyte via Al_2O_3 layer.
Keywords
EN
Year
Volume
123
Issue
2
Pages
368-370
Physical description
Dates
published
2013-02
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv123n2071kz
Identifiers
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