Tin/Tinoxide (Sn/SnO_2) Nanocomposites Thin Films as Negative-Electrode Materials for Li-Ion Batteries

• Authors: M. Alaf , D. Gultekin , H. Akbulut
• Languages of publication: EN

Abstracts

EN

In this study, tin/tinoxide (Sn/SnO_2) nanocomposites thin films were produced by thermal evaporation and plasma oxidation as anode materials for Li-ion batteries. To produce Sn/SnO_2 thin films, pure metallic tin (Sn) was thermally evaporated on the stainless steel substrates in argon atmosphere. The Sn films were subjected to plasma oxidation process at oxygen/argon gas mixture. Three different plasma oxidation times (30, 45, and 60 min) were used to investigate oxidation kinetics and physical and microstructural properties. The surface properties were studied by scanning electron microscopy and atomic force microscopy. For structural analysis, X-ray diffraction measurements were carried out. Sn/SnO_2 coated stainless steel substrates were used as the working electrode in coin-type (CR2016) test cells. The energy storage capacity Sn/SnO_2 electrodes were determined depending on the oxidation time and Sn:SnO_2 ratio.

Keywords

EN

64.70.fm; 73.61.At; 81.16.Pr; 82.47.Aa; 78.67.Sc

Discipline

• 81.16.Pr: Micro- and nano-oxidation(see also 82.37.Np Single molecule reaction kinetics)
• 64.70.fm: Thermodynamics studies of evaporation and condensation(for evaporation and condensation on surfaces, see 68.03.Fg)
• 78.67.Sc: Nanoaggregates; nanocomposites
• 82.47.Aa: Lithium-ion batteries
• 73.61.At: Metal and metallic alloys

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2013
• Volume: 123
• Issue: 2
• Pages: 323-325

Dates

published

2013-02

Contributors

author

M. Alaf

• Sakarya University, Dept. of Metallurgical & Materials Engineering, 54187, Sakarya, Turkey

author

D. Gultekin

• Sakarya University, Dept. of Metallurgical & Materials Engineering, 54187, Sakarya, Turkey

author

H. Akbulut

• Sakarya University, Dept. of Metallurgical & Materials Engineering, 54187, Sakarya, Turkey

References

• [1] C. de las Casas, W. Li, J. Power Sources 208, 74 (2012)
• [2] S.T. Chang, I.C. Leu, M.H. Hon, J. Alloys Comp. 403, 335 (2005)
• [3] Y. Kim, Y. Yoon, D. Shin, J. Anal. Appl. Pyrolysis 85, 557 (2009)
• [4] A. Sivashanmugam, T. Prem Kumar, N.G. Renganathan, S. Gopukumar, M. Wohlfahrt-Mehrens, J. Garche, J. Power Sources 144, 197 (2005)

Identifiers

DOI

10.12693/APhysPolA.123.323