PL EN


Preferences help
enabled [disable] Abstract
Number of results
2012 | 122 | 4 | 693-697
Article title

The Solid State Polymorphism and Dynamics of 2,3-Dimethylbutan-2-ol (2,3-DM-2-B)

Content
Title variants
Languages of publication
EN
Abstracts
EN
In the paper we present adiabatic calorimetry and dielectric spectroscopy results for 2,3-dimethylbutan-2-ol (2,3-DM-2-B), one of the isomers of neohexanol. For 2,3-DM-2-B we have detected the following phase transitions: C2 (249.8 K) → C1 (262 K) → Is. No glass phase was found. In both crystalline phases C2 and C1 three relaxation processes were detected. These processes are discussed in relation to the calorimetric studies.
Keywords
Publisher

Year
Volume
122
Issue
4
Pages
693-697
Physical description
Dates
published
2012-10
received
2012-02-29
(unknown)
2012-07-21
Contributors
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
References
  • [1] C.P. Smyth, Dielectric Behavior and Structure, McGraw-Hill, New York 1955
  • [2] H. Suga, J. Phys., Condens. Matter 15, 1 (2003)
  • [3] K. Adachi, H. Suga, S. Seki, Bull. Chem. Soc. Jap. 41, 1073 (1968)
  • [4] K. Adachi, H. Suga, S. Seki, Bull. Chem. Soc. Jap. 44, 78 (1971)
  • [5] A.C. Angell, Science 267, 1924 (1995)
  • [6] W. Kauzmann, Chem. Rev. 43, 219 (1948)
  • [7] E. Juszyńska, M. Massalska-Arodź, P.M. Zieliński, J. Ściesiński, Phase Transit. 79, 899 (2006)
  • [8] M. Massalska-Arodź, T. Nakamoto, T. Wasiutyński, J. Mayer, J. Krawczyk, M. Sorai, J. Chem. Thermodynam. 36, 877 (2004)
  • [9] J. Timmermans, J. Phys. Chem. Solids 18, 1 (1961)
  • [10] E. Juszyńska, M. Massalska-Arodź, I. Natkaniec, J. Mayer J. Krawczyk, Physica B 403, 109 (2008)
  • [11] E. Juszyńska, Ph.D. Thesis, Institute of Nuclear Physics PAN, Cracow 2008, accessible on: www.ifj.edu.pl/SD/rozprawy_dr/rozpr_Juszynska.pdf?lang=pl (in Polish)
  • [12] J. Krawczyk, control and acquisition software, unpublished
  • [13] Comprehensive Handbook of Calorimetry and Thermal Analysis, Ed. M. Sorai, Wiley, New York 2004
  • [14] F. Kremer, A. Schonhals, Broadband Dielectric Spectroscopy, Springer-Verlag, Heidelberg, 2003
  • [15] F. Aliev, Dielectrics Newsletter 20, 1 (2005)
  • [16] C. Hansen, F. Stickel, T. Berger, R. Richert, E.W. Fischer, J. Chem. Phys. 107, 1086 (1997)
  • [17] Li-Min Wang, R. Richert, J. Chem. Phys. 121, 11170 (2004)
  • [18] S. Havriliak, S. Negami, J. Pol. Sci. 14, 99 (1966)
  • [19] E. Juszyńska, P.M. Zieliński, M. Massalska-Arodź, J. Krawczyk, J. Ściesiński, Solid state polymorphism and dynamics of 2,2-dimethyl-1-butanol as studied by adiabatic calorimetry and dielectric spectroscopy, to be published
  • [20] E. Juszyńska, P.M. Zieliński, M. Massalska-Arodź, S. Napolitano, M. Wübbenhorst, J. Krawczyk, The solid state polymorphism and dynamics of 3,3-dimethylbutan-2-ol (3,3-DM-2-B), in preparation
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv122n410kz
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.