PL EN


Preferences help
enabled [disable] Abstract
Number of results
2012 | 122 | 4 | 693-697
Article title

The Solid State Polymorphism and Dynamics of 2,3-Dimethylbutan-2-ol (2,3-DM-2-B)

Content
Title variants
Languages of publication
EN
Abstracts
EN
In the paper we present adiabatic calorimetry and dielectric spectroscopy results for 2,3-dimethylbutan-2-ol (2,3-DM-2-B), one of the isomers of neohexanol. For 2,3-DM-2-B we have detected the following phase transitions: C2 (249.8 K) → C1 (262 K) → Is. No glass phase was found. In both crystalline phases C2 and C1 three relaxation processes were detected. These processes are discussed in relation to the calorimetric studies.
Keywords
Contributors
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
author
  • The H. Niewodniczański Institute of Nuclear Physics, PAS, E. Radzikowskiego 152, 31-342 Kraków, Poland
References
  • [1] C.P. Smyth, Dielectric Behavior and Structure, McGraw-Hill, New York 1955
  • [2] H. Suga, J. Phys., Condens. Matter 15, 1 (2003)
  • [3] K. Adachi, H. Suga, S. Seki, Bull. Chem. Soc. Jap. 41, 1073 (1968)
  • [4] K. Adachi, H. Suga, S. Seki, Bull. Chem. Soc. Jap. 44, 78 (1971)
  • [5] A.C. Angell, Science 267, 1924 (1995)
  • [6] W. Kauzmann, Chem. Rev. 43, 219 (1948)
  • [7] E. Juszyńska, M. Massalska-Arodź, P.M. Zieliński, J. Ściesiński, Phase Transit. 79, 899 (2006)
  • [8] M. Massalska-Arodź, T. Nakamoto, T. Wasiutyński, J. Mayer, J. Krawczyk, M. Sorai, J. Chem. Thermodynam. 36, 877 (2004)
  • [9] J. Timmermans, J. Phys. Chem. Solids 18, 1 (1961)
  • [10] E. Juszyńska, M. Massalska-Arodź, I. Natkaniec, J. Mayer J. Krawczyk, Physica B 403, 109 (2008)
  • [11] E. Juszyńska, Ph.D. Thesis, Institute of Nuclear Physics PAN, Cracow 2008, accessible on: www.ifj.edu.pl/SD/rozprawy_dr/rozpr_Juszynska.pdf?lang=pl (in Polish)
  • [12] J. Krawczyk, control and acquisition software, unpublished
  • [13] Comprehensive Handbook of Calorimetry and Thermal Analysis, Ed. M. Sorai, Wiley, New York 2004
  • [14] F. Kremer, A. Schonhals, Broadband Dielectric Spectroscopy, Springer-Verlag, Heidelberg, 2003
  • [15] F. Aliev, Dielectrics Newsletter 20, 1 (2005)
  • [16] C. Hansen, F. Stickel, T. Berger, R. Richert, E.W. Fischer, J. Chem. Phys. 107, 1086 (1997)
  • [17] Li-Min Wang, R. Richert, J. Chem. Phys. 121, 11170 (2004)
  • [18] S. Havriliak, S. Negami, J. Pol. Sci. 14, 99 (1966)
  • [19] E. Juszyńska, P.M. Zieliński, M. Massalska-Arodź, J. Krawczyk, J. Ściesiński, Solid state polymorphism and dynamics of 2,2-dimethyl-1-butanol as studied by adiabatic calorimetry and dielectric spectroscopy, to be published
  • [20] E. Juszyńska, P.M. Zieliński, M. Massalska-Arodź, S. Napolitano, M. Wübbenhorst, J. Krawczyk, The solid state polymorphism and dynamics of 3,3-dimethylbutan-2-ol (3,3-DM-2-B), in preparation
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv122n410kz
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.