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2012 | 121 | 2 | 324-327
Article title

White Light Snapshot of Non-Equilibrium High-Spin State in a Molecular Crystal

Content
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EN
Abstracts
EN
The spin-crossover compound [(TPA)Fe(TCC)]PF_6 was experimentally investigated using time-resolved optical pump and supercontinuum probe technique. Changes of VIS optical density at thermal equilibrium of a crystal with different high-spin/low-spin fractions are compared to changes recorded picoseconds after femtosecond laser excitation. A white light snapshot of the high-spin state at 180 K is extracted from time-resolved spectra. Our results indicate that the temperature of the electronic state affects the absorption spectra of high- and low-spin states.
Keywords
Year
Volume
121
Issue
2
Pages
324-327
Physical description
Dates
published
2012-02
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv121n207kz
Identifiers
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