Novel Route to Prepare Magnetic Material Co_3V_2O_8 and Structural Characterization

• Authors: G. Celik , F. Kurtulus , H. Guler
• Languages of publication: EN

Abstracts

EN

Co_3V_2O_8 is a member of kagomé staircase oxides, represented by general formula M_3V_2O_8 (M = Ni, Co, Mn). It attracted great attention due to strong magnetic anisotropy, magnetic phase transition, genuine macroscopic quantum effects, strong quantum fluctuations, low-temperature ferroelectricity, field-induced magnetic transitions, complicated phase diagram and displays long-range magnetic order because of geometrical frustration. Different routes to prepare the frustrated magnetic material was reported such as floating zone technique and conventional high temperature method. Co_3V_2O_8 (International Centre for Diffraction Data (ICDD): 16-675) was synthesized with Co_3O_4 (ICDD: 80-1536) as binary phase by microwave assisted preparation using Co(NO_3)_2 ·6H_2O and NH_4VO_3. The synthesized material was characterization by powder X-ray diffraction, the Fourier transform infrared spectroscopy, and thermogravimetric-differential thermal analysis.

Keywords

EN

07.85.-m; 32.30.Rj; 33.20.Ea; 61.43.Gt; 61.66.Fn; 65.40.-b; 75.47.Lx; 81.40.Gh; 82.33.Pt; 84.40.-x

Discipline

• 65.40.-b: Thermal properties of crystalline solids
• 61.66.Fn: Inorganic compounds
• 84.40.-x: Radiowave and microwave (including millimeter wave) technology(for microwave, submillimeter wave, and radiowave receivers and detectors, see 07.57.Kp; for microwave and radiowave spectrometers, see 07.57.Pt; for radiowave propagation, see 41.20.Jb)
• 82.33.Pt: Solid state chemistry
• 61.43.Gt: Powders, porous materials
• 32.30.Rj: X-ray spectra
• 75.47.Lx: Magnetic oxides
• 33.20.Ea: Infrared spectra
• 07.85.-m: X- and γ-ray instruments(for x- and γ-ray telescopes, see 95.55.Ka in astronomy; for x-ray beams and x-ray optics, see 41.50.+h)
• 81.40.Gh: Other heat and thermomechanical treatments

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2012
• Volume: 121
• Issue: 1
• Pages: 203-204

Dates

published

2012-01

Contributors

author

G. Celik

• Balikesir University, Science and Art Faculty, Chemistry Department, Cagis Yerleskesi, 10145 Balikesir, Turkey

author

F. Kurtulus

• Balikesir University, Science and Art Faculty, Chemistry Department, Cagis Yerleskesi, 10145 Balikesir, Turkey

author

H. Guler

• Balikesir University, Science and Art Faculty, Chemistry Department, Cagis Yerleskesi, 10145 Balikesir, Turkey

References

• 1. R. Szymczak, M. Baran, R. Diduszko, J. Fink-Finowicki, M. Gutowska, A. Szewczyk, H. Szymczak, J. Magn. Magn. Mater. 310, 1306 (2007)
• 2. N.R. Wilson, O.A. Petrenko, G. Balakrishnan, P. Manuel, B. Fak, J. Magn. Magn. Mater. 310, 1334 (2007)
• 3. R. Szymczak, P. Aleshkevyh, C.P. Adams, S.N. Barilo, A.J. Berlinsky, J.P. Clancy, V. Domuchowski, J.F. Finowicki, B.D. Gaulin, M. Ramazanoglu, S.V. Shiryaev, Z. Yamani, H. Szymczak, J. Magn. Magn. Mater. 321, 793 (2009)
• 4. Z. He, Y. Ueda, M. Itoh, J. Cryst. Growth 297, 1 (2006)
• 5. F. Yen, R.P. Chaudhury, E. Galstyan, B. Lorentz, Y.Q. Wang, Y.Y. Sun, C.W. Chu, Physica B 403, 1487 (2008)
• 6. C.C. Hwang, T.Y. Wu, J. Wan, J.S. Tsai, Mater. Sci. Eng. B 111, 49 (2004)
• 7. K.J., Rao, B. Vaidhyanathan, M. Ganguli, P.A. Ramakrishnan, Chem. Mater. 11, 882 (1999)
• 8. M. Sertkol, M.Sc. Thesis, Fatih University, Istanbul 2008
• 9. O. Carp, L. Patron, A. Reler, Mater. Chem. Phys. 101, 142 (2007)
• 10. P. Pigram, J. Am. Chem. Soc. 36, 123 (1993)
• 11. D. Xiao, S. Wang, Y. Hou, E. Wang, Y. Li, H. An, L. Xu, C. Hu, J. Mol. Struct. 692, 107 (2004)
• 12. M. Sertkol, Y. Köseoğlu, A. Baykal, H. Kavas, A. Bozkurt, M.S. Toprak, J. Alloys Comp. 486, 325 (2009)

Identifiers

DOI

10.12693/APhysPolA.121.203