PL EN


Preferences help
enabled [disable] Abstract
Number of results
2011 | 120 | 3 | 541-544
Article title

A Product Operator Theory of DEPTQ NMR Spectroscopy for IS_{n} (I = 1/2; S = 1; n = 0, 1, 2, 3) Spin Systems

Content
Title variants
Languages of publication
EN
Abstracts
EN
Distortionless enhancement by polarization transfer including the detection of quaternary nuclei is a carbon-editing pulse NMR experiment. In this experiment multiplicity information for all carbons including quaternary carbons are obtained. In the present study, analytical descriptions of DEPTQ NMR experiment have been investigated for weakly coupled IS_{n} (I = 1/2; S = 1; n = 0, 1, 2, 3) spin systems by using the product operator theory. Then, the theoretical discussion and the experimental suggestions for sub-spectral editing of C, CD, CD_2 and CD_3 groups have been presented. The comparison of the obtained results with those of the basic distortionless enhancement by polarization transfer NMR experiment has been also performed for CD_{n} groups. It is shown that DEPTQ experiment can be also used for CD_{n} groups.
Keywords
EN
Publisher

Year
Volume
120
Issue
3
Pages
541-544
Physical description
Dates
published
2011-09
received
2008-11-18
(unknown)
2011-04-20
Contributors
author
  • Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Samsun, Turkey
author
  • Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Samsun, Turkey
author
  • Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Samsun, Turkey
References
  • 1. O.W. Sorensen, Prog. NMR Spectrosc. 21, 503 (1989)
  • 2. P. Nolis, T. Parella, Curr. Analty. Chem. 3, 47 (2007)
  • 3. D.M. Doddrell, D.T. Pegg, M.R. Bendall, J. Magn. Reson. 48, 323 (1982)
  • 4. N. Chandrakumar, J. Magn. Reson. 60, 28 (1984)
  • 5. R. Burger, P. Bigler, J. Magn. Reson. 135, 529 (1998)
  • 6. P. Bigler, R. Kümmerle, W. Bermel, Magn. Reson. Chem. 45, 469 (2007)
  • 7. P. Bigler, Spectrosc. Lett. 41, 162 (2008)
  • 8. O.W. Sørensen, G.W. Eich, M.H. Levitt, G. Bodenhausen, R.R. Ernst, Prog. NMR Spectrosc. 16, 163 (1983)
  • 9. O.W. Sørensen, R.R. Ernst, J. Magn. Reson. 51, 477 (1983)
  • 10. N. Chandrakumar, S. Subramanian, Modern Techniques in High Resolution FT NMR, Springer-Verlag, New York 1987
  • 11. R.R. Ernst, G. Bodenhausen, A. Wokaun, Principles of Nuclear Magnetic Resonance in One and Two Dimensions, Clarendon Press, Oxford 1987
  • 12. N. Chandrakumar, Spin-1 NMR, Springer, Berlin 1996
  • 13. T.T. Nakashima, R.E.D. McClung, B.K. John, J. Magn. Reson. 58, 27 (1984)
  • 14. A. Gençten, F. Köksal, Spectrosc. Lett. 30, 71 (1997)
  • 15. A. Gençten, T. Özdoğan, F. Koksal, Spectrosc. Lett. 31, 981 (1998)
  • 16. A. Gençten, Ö. Tezel, A. Köroğlu, Appl. Magn. Reson. 20, 265 (2001)
  • 17. İ. Şaka, Ö. Tezel, A. Gençten, Z. Naturforsch. 58a, 139 (2003)
  • 18. A. Tokatlı, A. Gençten, M. Şahin, Ö. Tezel, S. Bahçeli, J. Magn. Reson. 169, 68 (2004)
  • 19. A. Gençten, İ. Şaka, Mol. Phys. 104, 2983 (2006)
  • 20. İ. Şaka, A. Gençten, J. Mol. Struct. 834-836, 521 (2007)
  • 21. İ. Şaka, A. Gençten, Z. Naturforsch. 62a, 259 (2007)
  • 22. T. Özdoğan, M. Orbay, Spectrosc. Lett. 35, 447 (2002)
  • 23. S. Wolfram, The Mathematica Book, 3rd ed., Wolfram Media/Cambridge University Press, Cambridge 1996
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv120n332kz
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.