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2011 | 119 | 5 | 711-713
Article title

Spin Crossover in Cu_{x}Co_{y}Cr_{z}Se_4 Semiconductors

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EN
Abstracts
EN
Magnetization and magnetic susceptibility measured in the zero-field-cooled mode were used to study the spin crossover transition in polycrystalline Cu_{x}Co_{y}Cr_{z}Se_4 compounds. With increasing Co content a transition from ferromagnetic order via ferrimagnetic one to antiferromagnetic-like behaviour was observed. This transition is accompanied with a lowering symmetry from cubic to monoclinic and for the latter the spin crossover phenomenon occurs. These results are considered in a framework of the ligand-field split and the spin-orbit coupling.
Keywords
EN
Publisher

Year
Volume
119
Issue
5
Pages
711-713
Physical description
Dates
published
2011-05
Contributors
author
  • Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland
author
  • Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland
author
  • The Henryk Niewodniczański Institute of Nuclear Physics, Polish Academy of Sciences, E. Radzikowskiego 152, 31-342 Kraków, Poland
author
  • International Laboratory of High Magnetic Fields and Low Temperatures, Gajowicka 95, 53-529 Wrocław, Poland
author
  • Institute of Chemistry, University of Silesia, Szkolna 9, 40-006 Katowice, Poland
  • Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv119n543kz
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