EN
In the paper the results of investigations of X-ray excitation spectra, thermostimulated luminescence and the influence of light illumination on the thermoluminescence glow curves of pure and Tb-doped PbWO_{4} crystals are presented. It is suggested that the F^{-}-centres are formed in PbWO_{4} crystals at filling oxygen vacancies near Pb^{3+} ions to three electrons under X-ray irradiation at 90 K. The nature of 108 K thermostimulated luminescence peak is connected with the [(WO_{3} + F^{-})-Pb^{3+}] associations. It was established that thermal or optical destruction of this peak leads to appearance of the radiative transitions of excitons localized near the [(WO_{3} + F)-Pb^{2+}] complex centres.