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In the paper the results of investigations of X-ray excitation spectra, thermostimulated luminescence and the influence of light illumination on the thermoluminescence glow curves of pure and Tb-doped PbWO_{4} crystals are presented. It is suggested that the F^{-}-centres are formed in PbWO_{4} crystals at filling oxygen vacancies near Pb^{3+} ions to three electrons under X-ray irradiation at 90 K. The nature of 108 K thermostimulated luminescence peak is connected with the [(WO_{3} + F^{-})-Pb^{3+}] associations. It was established that thermal or optical destruction of this peak leads to appearance of the radiative transitions of excitons localized near the [(WO_{3} + F)-Pb^{2+}] complex centres.
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143-145
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published
2010-01
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- Lviv I. Franko National University, Universitetska st. 1, 79000 Lviv, Ukraine
author
- Lviv I. Franko National University, Universitetska st. 1, 79000 Lviv, Ukraine
author
- Lviv I. Franko National University, Universitetska st. 1, 79000 Lviv, Ukraine
author
- Lviv I. Franko National University, Universitetska st. 1, 79000 Lviv, Ukraine
References
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Document Type
Publication order reference
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YADDA identifier
bwmeta1.element.bwnjournal-article-appv117z127kz