EN
The plasma chemical etching of Si and SiO_{2} in SF_{6}+O_{2} plasma is considered. The concentrations of plasma components are calculated by fitting the experimental data. The derived concentrations of plasma components are used for the calculation of Si and SiO_{2} etching rates. It is found that the reaction probabilities of F atoms with Si atoms and SiO_{2} molecules are equal to ε = (8.75 ± 0.41) × 10^{-3} and ε = (7.18 ± 0.45) × 10^{-5}, respectively. The influence of O_{2} addition to SF_{6} plasma on the etching rate of Si is determined.