Solvation of Alcohols in n-Heptane and n-Propanol from the Acoustic Passynski Method

• Authors: J. Gliński , A. Burakowski
• Languages of publication: EN

Abstracts

EN

The method of Passynski of calculating the solvation numbers from compressibility was applied to solutions of short-chained normal alcohols in n-heptane and n-propanol. The dependences of solvation numbers on length of the solute molecules are surprisingly similar for both solvents. Applicability of the acoustic method for determining the solvation numbers in nonaquous systems, as well as for investigation of intermolecular interactions in them was proved. Some structural similarity of associated alcohol and hydrocarbon in liquid state is suggested.

Keywords

EN

43.35.Bf; 43.35.+d; 61.20.-p; 61.20.Qg

Discipline

• 61.20.-p: Structure of liquids
• 43.35.+d: Ultrasonics, quantum acoustics, and physical effects of sound
• 61.20.Qg: Structure of associated liquids: electrolytes, molten salts, etc.

• Publisher: Institute of Physics, Polish Academy of Sciences
• Journal: Acta Physica Polonica A
• Year: 2008
• Volume: 114
• Issue: 6A
• Pages: A-109-A-113

Dates

published

2008-12

Contributors

author

J. Gliński

• Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

author

A. Burakowski

• Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

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Identifiers

DOI

10.12693/APhysPolA.114.A-109