Structural Studies with the Use of XRD and Mössbauer Spectroscopy οf Bi_5Ti_3FeO_{15} Ceramic Powders Obtained by Mechanical Synthesis

• Authors: G. Dercz , J. Rymarczyk , A. Hanc , K. Prusik , R. Babilas , L. Pająk , J. Ilczuk
• Languages of publication: EN

Abstracts

EN

In this paper the structural and Mössbauer spectral properties of multiferroic ceramic Bi_5Ti_3FeO_{15} powders prepared by high-energy ball milling of polycrystalline precursor material (mixture of Bi_2O_3, TiO_2 and Fe_2O_3 powders) are presented. Mechanical synthesis was performed by high-energy vibratory mill. The X-ray diffraction methods were applied for the structure characterization of the studied samples. The parameters of diffraction line profiles were determined by PRO-FIT Toraya procedure. The crystallite sizes and lattice distortions were analyzed using the Williamson-Hall method. Investigations of hyperfine interactions in the studied materials were carried out by the Mössbauer spectroscopy. The powder morphology was analyzed by scanning electron microscopy and transmission electron microscopy techniques. It was found that during high-energy milling phase transitions, a decrease in crystallite size and amorphization process are observed.

Keywords

EN

61.05.Qr; 61.05.C-; 61.05.J-; 81.07.Bc; 81.20.Wk

Discipline

• 81.20.Wk: Machining, milling
• 61.05.Qr: Magnetic resonance techniques; Mössbauer spectroscopy (for structure determination only)
• 81.07.Bc: Nanocrystalline materials
• 61.05.C-: X-ray diffraction and scattering(for x-ray diffractometers, see 07.85.Jy; for x-ray studies of crystal defects, see 61.72.Dd, Ff)
• 61.05.J-: Electron diffraction and scattering(for electron diffractometers, see 07.78.+s)

• Journal: Acta Physica Polonica A
• Year: 2008
• Volume: 114
• Issue: 6
• Pages: 1623-1629

Dates

published

2008-12

Contributors

author

G. Dercz

• Institute of Materials Science, University of Silesia, Bankowa 12, 40-007 Katowice, Poland

author

J. Rymarczyk

• Department of Material Science, University of Silesia, Żeromskiego 3, 41-200 Sosnowiec, Poland

author

A. Hanc

• Institute of Materials Science, University of Silesia, Bankowa 12, 40-007 Katowice, Poland

author

K. Prusik

• Institute of Materials Science, University of Silesia, Bankowa 12, 40-007 Katowice, Poland

author

R. Babilas

• Institute of Engineering Materials and Biomaterials, Silesian University of Technology, Konarskiego 18a, 44-200 Gliwice, Poland

author

L. Pająk

• Institute of Materials Science, University of Silesia, Bankowa 12, 40-007 Katowice, Poland

author

J. Ilczuk

• Department of Material Science, University of Silesia, Żeromskiego 3, 41-200 Sosnowiec, Poland

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Identifiers

DOI

10.12693/APhysPolA.114.1623