Journal
Article title
Authors
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Abstracts
Free energy and entropy were calculated for molecules of different shapes in gas phase and under small pressure. The values of the thermodynamic functions were found strongly dependent on the molecular shape. The results obtained were applied to predict the route of internal energy deactivation as well as the preferred form of the molecules examined.
Discipline
- 05.20.-y: Classical statistical mechanics
- 05.70.-a: Thermodynamics(see also section 64 Equations of state, phase equilibria, and phase transitions, and section 65 Thermal properties of condensed matter; for chemical thermodynamics, see 82.60.-s; for thermodynamics of plasmas, see 52.25.Kn; for thermodynamic properties of quantum fluids, see 67.25.bd, and 67.30.ef; for thermodynamics of nanoparticles, see 82.60.Qr, and 65.80.-g; for thermodynamic processes in astrophysics, see 95.30.Tg; for thermodynamics in volcanology, see 91.40.Pc)
Journal
Year
Volume
Issue
Pages
1111-1115
Physical description
Dates
published
2008-04
received
2007-06-03
Contributors
author
- Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland
author
- Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland
References
- 1. P. Atkins, Physical Chemistry, Oxford University Press, Oxford 1998
- 2. S. Gladstone, Theoretical Chemistry, Van Nostrand Co., Princeton 1961
- 3. K. Huang, Statistical Mechanics, Wiley, New York 1963
- 4. G. Herzberg, Molecular Spectra and Molecular Structure, Vols. I-III, Van Nostrand Co., New York 1950
- 5. H.W. Kroto, Molecular Rotational Spectra, Wiley, London 1979
- 6. J. Makarewich, Mol. Phys. 68, 107 (1989)
- 7. J. Stanek, J. Konarski, Int. J. Bif. Chaos 10, 257 (2000)
- 8. Landolt-Bornstein, Zalenverte und Funktionen, Neue Serie, Grupe II, Band 6, Molekul Konstanten, Springer Verlag, Berlin 1974
- 9. K.P. Huber, G. Herzberg, Molecular Spectra and Molecular Structure, IV, Constants of Two Atomic Molecules, Van Nostrand, Toronto 1979
- 10. J. Konarski, Israel J. Chem. 43, 287 (2003)
- 11. J. Konarski, Phase Transit. 80, 511 (2007)
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv113n401kz