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The ordered PbSc_{1/2}Nb_{1/2}O_3 ceramics were studied by THz transmission spectroscopy in the temperature range of 80-300 K. Below ferroelectric phase transition temperature the strength of central mode gradually decreases and gives evidence for a mixed displacive and order-disorder character of the transitions. Ferroelectric phase transition is connected with an abrupt freezing and rise of polar nanoregions into ferroelectric domains.
Institute of Solid State Physics, University of Latvia, 8 Kengaraga str., Riga, Latvia
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