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2008 | 113 | 1 | 481-484
Article title

[Ni(en)(H_2O)_4][SO_4]·2H_2O - an S = 1 Molecular Magnet with Easy-Plane Anisotropy

Content
Title variants
Languages of publication
EN
Abstracts
EN
Structural analysis of [Ni(en)(H_2O)_4][SO_4]·2H_2O was performed and it suggests that the crystal field should play a dominant role in the magnetic properties of the system. This conjecture coincides well with the specific heat and susceptibility behaviour. The analysis confirmed that the compound can be treated as a spin 1 single molecule magnet with nonmagnetic ground state introduced by easy-plane single-ion anisotropy D/k_B≈11 K and neglecting in-plane anisotropy E/D <0.1.
Keywords
EN
Year
Volume
113
Issue
1
Pages
481-484
Physical description
Dates
published
2008-01
received
2007-07-09
References
  • 1. G. Misguich, C. Lhuillier, Frustrated Spin Systems, Ed. H.T. Diep, World Sci., Singapore 2005
  • 2. M. Kajňaková, M. Orendáč, A. Orendáčová, A. Vlček, J.Černák, O.V. Kravchyna, A.G. Anders, M. Bałanda, J.-H. Park, A. Feher, M W. Meisel, Phys. Rev. B 71, 014435 (2005)
  • 3. P.C. Healy, J.M. Patrick, A.H. White, Aust. J. Chem. 37, 921 (1984)
  • 4. R. Ivaniková, R. Boča, L. Dlháň, H. Fuess, A. Mašlejová, V. Mrázová, I. Svoboda, J. Titiš, Polyhedron 25, 3261 (2006)
Document Type
Publication order reference
YADDA identifier
bwmeta1.element.bwnjournal-article-appv113n1118kz
Identifiers
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