Spectral Investigations of Fullerene-Porphyrin Complexes

• Authors: B. Barszcz , A. Bogucki , B. Laskowska , R. Ion , A. Graja
• Languages of publication: EN

Abstracts

EN

Spectral investigations of someμ-oxo-dimer complexes of trivalent metals (Mn, Fe) with two different ligands: tetraphenylporphyrin and tetranaphthylporphyrin (TNP), and fullerene (C_{60} and C_{70}) complexes withμ-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)_2O dimer, where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discussion of the main electronic and vibrational bands observed in the UV-Vis-IR and Raman spectra of both classes of fullerene-porphyrin systems is given. Experimental data are completed with the quantum chemical calculations of MnTNP^+ component.

Keywords

EN

33.20.-t; 33.20.Ea; 33.20.Fb; 33.20.Kf; 33.20.Tp; 36.40.-c; 31.15.Ar; 33.15.Bh

Discipline

• 33.15.Bh: General molecular conformation and symmetry; stereochemistry
• 33.20.Kf: Visible spectra
• 33.20.Tp: Vibrational analysis
• 33.20.Ea: Infrared spectra
• 33.20.Fb: Raman and Rayleigh spectra (including optical scattering)
• 33.20.-t: Molecular spectra(see also 78.47.J- Ultrafast spectroscopy (<1>
• 36.40.-c: Atomic and molecular clusters(see also 61.46.-w Nanoscale materials in condensed matter)

• Journal: Acta Physica Polonica A
• Year: 2007
• Volume: 112
• Issue: S
• Pages: S-143-S-152

Dates

published

2007-12

received

2007-10-26

Contributors

author

B. Barszcz

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

A. Bogucki

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

B. Laskowska

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

author

R. Ion

• VALAHIA University of Targoviste, 130082 Targoviste, Romania

author

A. Graja

• Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland

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Identifiers

DOI

10.12693/APhysPolA.112.S-143