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Abstracts
Spectral investigations of someμ-oxo-dimer complexes of trivalent metals (Mn, Fe) with two different ligands: tetraphenylporphyrin and tetranaphthylporphyrin (TNP), and fullerene (C_{60} and C_{70}) complexes withμ-oxobis[5,10,15,20-tetraarylporphyrinatometal (III)] (TXP-M)_2O dimer, where M = Fe, Mn and X = phenyl or naphthyl, are presented. Discussion of the main electronic and vibrational bands observed in the UV-Vis-IR and Raman spectra of both classes of fullerene-porphyrin systems is given. Experimental data are completed with the quantum chemical calculations of MnTNP^+ component.
Discipline
- 33.15.Bh: General molecular conformation and symmetry; stereochemistry
- 33.20.Kf: Visible spectra
- 33.20.Tp: Vibrational analysis
- 33.20.Ea: Infrared spectra
- 33.20.Fb: Raman and Rayleigh spectra (including optical scattering)
- 33.20.-t: Molecular spectra(see also 78.47.J- Ultrafast spectroscopy (<1>
- 36.40.-c: Atomic and molecular clusters(see also 61.46.-w Nanoscale materials in condensed matter)
Journal
Year
Volume
Issue
Pages
S-143-S-152
Physical description
Dates
published
2007-12
received
2007-10-26
Contributors
author
- Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland
author
- Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland
author
- Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland
author
- VALAHIA University of Targoviste, 130082 Targoviste, Romania
author
- Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznań, Poland
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv112n711kz