Electric Dipole Moments of Acetone and of Acetic Acid Measured in Supersonic Expansion

Dorosh, O.; Kisiel, Z.

doi:10.12693/APhysPolA.112.S-95

Journal

Acta Physica Polonica A

2007 | 112 | S | S-95-S-104

Article title

Electric Dipole Moments of Acetone and of Acetic Acid Measured in Supersonic Expansion

Authors

O. Dorosh , Z. Kisiel

Content

Full texts:

http://przyrbwn.icm.edu.pl/APP/PDF/112/a112z707.pdf [remote]

Title variants

Languages of publication

Abstracts

Precise values for electric dipole moments of isolated acetone and acetic acid molecules were determined from the Stark effect measurements made on lowest J rotational transitions at conditions of supersonic expansion. The new results areμ_{tot} =μ_b =2.9345(22) D for acetone from measurements on the 1_{11}← 1_{01} transition, andμ_a =0.8631(8),μ_b =1.4345(11),μ_{tot} =1.6741(10) D for acetic acid, from measurements on 1_{11}← 0_{00} and 1_{01}←0_{00} transitions. A comparison with previous determinations and with results of quantum chemical calculations is presented.

Keywords

31.15.Ar 32.10.Dk 32.30.Bv 32.60.+i 33.15.Kr 33.1.Mt 33.20.Bx 33.20.Sn

Discipline

Publisher

Institute of Physics, Polish Academy of Sciences

Journal

Acta Physica Polonica A

Year

2007

Volume

112

Issue

Pages

S-95-S-104

Physical description

Dates

published

2007-12

received

2007-10-26

Contributors

author

O. Dorosh

Institute of Physics, Polish Academy of Science, al. Lotników 32/46, 02-668 Warszawa, Poland

author

Z. Kisiel

Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warszawa, Poland

References

1. W. Gordy, R.L. Cook, Microwave Molecular Spectra, Wiley, New York 1984
2. P. Groner, S. Albert, E. Herbst, F.C. De Lucia, F.J. Lovas, B.J. Drouin, J.C. Pearson, Astrophys. J. Suppl. Ser., 142, 145, 2002
3. V.V. Ilyushin, E.A. Alekseev, S.F. Dyubko, S.V. Podnos, I. Kleiner, L. Margules, G. Wlodarczak, J. Demaison, J. Cosleou, B. Mate, E.N. Karyakin, G.Yu. Golubiatnikov, G.T. Fraser, R.D. Suenram, J.T. Hougen, J. Mol. Spectrosc., 205, 286, 2001
4. F. Combes, M. Gerin, A.S. Wootten, G. Wlodarczak, F. Clausset, P.J. Encrenaz, Astron. Astrophys., 180, L13, 1987
5. D.M. Mehringer, L.E. Snyder, Y. Miao, F.J. Lovas, Astrophys. J., 480, L71, 1997
6. J.D. Swalen, C.C. Costain, J. Chem. Phys., 31, 1562, 1959
7. R. Peter, H. Dreizler, Z. Naturforsch., 20a, 301, 1965
8. L.C. Krisher, E. Saegebarth, J. Chem. Phys., 54, 4553, 1971
9. Z. Kisiel, J. Kosarzewski, L. Pszczólkowski, Acta Phys. Pol. A, 92, 507, 1997
10. T.J. Balle, W.H. Flygare, Rev. Sci. Instrum., 52, 33, 1981
11. Z. Kisiel, J. Kosarzewski, B.A. Pietrewicz, L. Pszczólkowski, Chem. Phys. Lett., 325, 523, 2000
12. Z. Kisiel, E. Bialkowska-Jaworska, O. Desyatnyk, B.A. Pietrewicz, L. Pszczólkowski, J. Mol. Spectrosc., 208, 113, 2001
13. L.H. Coudert, F.J. Lovas, R.D. Suenram, J.T. Hougen, J. Chem. Phys., 87, 6290, 1987
14. M. Canagaratna, M.E. Ott, K.R. Leopold, Chem. Phys. Lett., 281, 63, 1997
15. T. Emilsson, H.S. Gutowsky, G. de Oliveira, C.E. Dykstra, J. Chem. Phys., 112, 1287, 2000
16. M. Schnell, D. Banser, J.-U. Grabow, Rev. Sci. Instrum., 75, 2111, 2004
17. Z. Kisiel, PROSPE -- Programs for ROtational SPEctroscopy, available from http://info.ifpan.edu.pl/∼kisiel/prospe.htm
18. J.K.G. Watson in: Vibrational Spectra and Structure, Ed. J.R. Durig, Vol. 6, Elsevier, New York 1977, p. 1
19. P. Groner, J. Mol. Struct., 550-551, 473, 2000
20. D.R. Herschbach, J. Chem. Phys., 31, 91, 1959
21. A.A. Granovsky, PC-GAMESS program, available from http://classic.chem.msu.su/gran/gamess/index.html
22. M.W. Schmidt, K.K. Baldridge, J.A. Boatz, S.T. Elbert, M.S. Gordon, J.H. Jensen, S. Koseki, N. Matsunaga, K.A. Nguyen, S.J. Su, T.L. Windus, M. Dupuis, J.A. Montgomery, J. Comput. Chem., 14, 1347, 1993
23. Extensible Computational Chemistry Environment Basis Set Database, developed and distributed by the Molecular Science Computing Facility, Environmental and Molecular Sciences Laboratory which is part of the Pacific Northwest Laboratory, P.O. Box 999, Richland, Washington 99352, USA, and funded by the U.S. Department of Energy, available from http://www.emsl.pnl.gov/forms/basisform.html
24. Z. Kisiel, O. Desyatnyk, L. Pszczólkowski, S.B. Charnley, P. Ehrenfreund, J. Mol. Spectrosc., 217, 115, 2003
25. Z. Kisiel, O. Desyatnyk, E. Bialkowska-Jaworska, L. Pszczólkowski, Phys. Chem. Chem. Phys., 5, 820, 2003
26. O. Desyatnyk, L. Pszczólkowski, S. Thorwirth, T.M. Krygowski, Z. Kisiel, Phys. Chem. Chem. Phys., 7, 1708, 2005; 7, 2080, 2005
27. E. Bialkowska-Jaworska, Z. Kisiel, L. Pszczólkowski, J. Mol. Spectrosc., 238, 72, 2006

Document Type

Publication order reference

Identifiers

DOI

10.12693/APhysPolA.112.S-95

YADDA identifier

bwmeta1.element.bwnjournal-article-appv112n707kz