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2006 | 110 | 4 | 495-504
Article title

Dielectric Relaxation in Hydrogen Bonded Urea-Based Supramolecular Polymer N,N'-di(2,2-dipentylheptyl)urea

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Abstracts
EN
Results of the dielectric relaxation studies, performed for supramolecular polymer formed by N,N'-di(2,2-dipentylheptyl)urea dissolved in carbon tetrachloride, are presented. The measurements were done for N,N'-di(2,2-dipentylheptyl)urea concentration up to about 7% (in mole fraction) in the frequency region from 100 kHz to 100 MHz and at the temperatures from 5ºC to 50ºC. The analysis of the experimental data were performed with the Havriliak-Negami equation. In the studied range of N,N'-di(2,2-dipentylheptyl)urea concentration and temperature, the obtained values of exponentsα andβ of the Havriliak-Negami equation are equal to 0.9±0.1 and 0.7±0.1, respectively, showing an anomaly in the dielectric relaxation behavior close to the Davidson-Cole type. Two examples of the modeling of dielectric properties of the supramolecular polymer solutions were presented.
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Contributors
author
  • Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Poznań, Poland
author
  • Laboratoire de Chimie des Polymères, UMR 7610, Université Pierre et Marie Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
author
  • Groupe de Physique Statistique et Moléculaire, MEPS, Université de Perpignan, 52 Avenue Paul Alduy, 66860 Perpignan Cedex, France
author
  • Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Poznań, Poland
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.bwnjournal-article-appv110n406kz
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